2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant

Mekhman S. Yusubov; Natalia S. Soldatova; Pavel S. Postnikov; Rashid R. Valiev; Akira Yoshimura; Thomas Wirth; Victor N. Nemykin; Viktor Zhdankin

doi:10.1039/c9cc04203b

2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant

Mekhman S. Yusubov, Natalia S. Soldatova, Pavel S. Postnikov, Rashid R. Valiev, Akira Yoshimura, Thomas Wirth, Victor N. Nemykin, Viktor Zhdankin

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.

Original language	English (US)
Pages (from-to)	7760-7763
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	54
DOIs	https://doi.org/10.1039/c9cc04203b
State	Published - 2019

Bibliographical note

Funding Information:
This work was supported by research grants from the NSF (CHE-1759798), the Royal Society (IE160304), and the NSERC. M. S. Y. and A. Y. are also thankful to the Russian Science Foundation (RSF-16-13-10081-P).

Publisher Copyright:
© 2019 The Royal Society of Chemistry.

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abstract = "A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.",

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AU - Soldatova, Natalia S.

AU - Postnikov, Pavel S.

AU - Valiev, Rashid R.

AU - Yoshimura, Akira

AU - Wirth, Thomas

AU - Nemykin, Victor N.

AU - Zhdankin, Viktor

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2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant

Abstract

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