In a spin: Transient peroxo iron complexes have been characterized by the means of Mössbauer and HF-EPR spectroscopies. Complex 1 has an unexpected S = 2 ground state resulting from the coupling between the S = 5/2 and S = 1/2 iron(III) ions.
|Original language||English (US)|
|Number of pages||4|
|Journal||Angewandte Chemie - International Edition|
|State||Published - Feb 15 2002|
- EPR spectroscopy
- O-O activation
- Peroxo ligands