A dramatic push effect on the homolysis of FeIII(OOR) intermediates to form non-heme FeIV=O complexes

József Kaizer; Miquel Costas; Lawrence Que

doi:10.1002/anie.200351694

A dramatic push effect on the homolysis of Fe^III(OOR) intermediates to form non-heme Fe^IV=O complexes

József Kaizer, Miquel Costas, Lawrence Que

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

84 Scopus citations

Abstract

A pushy Lewis base: Previously unobserved non-heme Fe^IV=O intermediates can be trapped in the decay of Fe^IIIOOR species by the addition of Lewis bases (represented by the green sphere) that promote O-O bond homolysis (see picture; Fe purple, O red).

Original language	English (US)
Pages (from-to)	3671-3673
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	31
DOIs	https://doi.org/10.1002/anie.200351694
State	Published - Aug 11 2003

Keywords

High-valent species
Iron
Kinetics
Oxo ligands
Push effect

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10.1002/anie.200351694

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abstract = "A pushy Lewis base: Previously unobserved non-heme FeIV=O intermediates can be trapped in the decay of FeIIIOOR species by the addition of Lewis bases (represented by the green sphere) that promote O-O bond homolysis (see picture; Fe purple, O red).",

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KW - Kinetics

KW - Oxo ligands

KW - Push effect

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