Abstract
An elusive goal—that of enforcing the interaction of an electron donor at a polyoxometalate acceptor in solution—has been realized. Covalent tethering of a ferrocenyl group to the hexamolybdate cluster was achieved by the introduction of a ferrocenylimido (FcN) ligand, yielding the anion [(FcN)Mo6O18]2− 1 (shown schematically on the right). The simple synthesis of 1 should also be applicable to other systems and thus may provide new opportunities in the field of charge transfer salts with polyoxometalate anions. (Figure Presented.)
Original language | English (US) |
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Pages (from-to) | 2547-2548 |
Number of pages | 2 |
Journal | Angewandte Chemie International Edition in English |
Volume | 34 |
Issue number | 22 |
DOIs | |
State | Published - Dec 1 1995 |
Keywords
- complexes with ferrocenyl ligands
- donor–acceptor systems
- molybdenum compounds
- polyoxometalates