A Model for α‐Keto Acid Dependent Nonheme Iron Enzymes: Structure and Reactivity of [Fe 2II(Me2hdp)2(bf)](ClO4)

Yu‐Min ‐M Chiou; Lawrence Que

doi:10.1002/anie.199418861

A Model for α‐Keto Acid Dependent Nonheme Iron Enzymes: Structure and Reactivity of [Fe 2II(Me₂hdp)₂(bf)](ClO₄)

Yu‐Min ‐M Chiou, Lawrence Que

Chemistry (Twin Cities)

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Abstract

The bis(μ‐phenolato)diiron(II) complex 1 is a model compound for nonheme iron enzymes that use α‐keto acids as cofactors. Complex 1 undergoes immediate oxidative decarboxylation upon exposure to dioxygen at a rate which is three to four orders of magnitude faster than those observed for other compounds of this type. The formula of the ligand is given under that of 1. (Figure Presented.)

Original language	English (US)
Pages (from-to)	1886-1888
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	33
Issue number	18
DOIs	https://doi.org/10.1002/anie.199418861
State	Published - Sep 30 1994

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A Model for α‐Keto Acid Dependent Nonheme Iron Enzymes: Structure and Reactivity of [Fe 2II(Me₂hdp)₂(bf)](ClO₄)

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