A novel catalytic pathway for perfluoroacyl peroxide synthesis

Pavel A. Krasutsky; Igor V. Kolomitsyn; Robert M. Carlson

doi:10.1021/ol016338v

A novel catalytic pathway for perfluoroacyl peroxide synthesis

Pavel A. Krasutsky, Igor V. Kolomitsyn, Robert M. Carlson

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Abstract

matrix presented A new catalytic method for synthesis of bis(perfluoroacyl) peroxides (BPFAP) was elaborated by using hydrogen peroxide and perfluoroacyl anhydrides. The desired BPFAP were formed quantitatively in situ when perfluoroacyl anhydride was mixed with hydrogen peroxide (ratio ≥ 2:1) in the presence of a catalytic amount of the carboxylate R_fCOO^- M⁺. The essentially irreversible character of this process was shown experimentally and supported on the basis of DFT calculations. The synthesis of new acetyltrifluoroacetyl peroxides is also described.

Original language	English (US)
Pages (from-to)	2997-2999
Number of pages	3
Journal	Organic Letters
Volume	3
Issue number	19
DOIs	https://doi.org/10.1021/ol016338v
State	Published - Sep 20 2001

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title = "A novel catalytic pathway for perfluoroacyl peroxide synthesis",

abstract = "matrix presented A new catalytic method for synthesis of bis(perfluoroacyl) peroxides (BPFAP) was elaborated by using hydrogen peroxide and perfluoroacyl anhydrides. The desired BPFAP were formed quantitatively in situ when perfluoroacyl anhydride was mixed with hydrogen peroxide (ratio ≥ 2:1) in the presence of a catalytic amount of the carboxylate RfCOO- M+. The essentially irreversible character of this process was shown experimentally and supported on the basis of DFT calculations. The synthesis of new acetyltrifluoroacetyl peroxides is also described.",

author = "Krasutsky, {Pavel A.} and Kolomitsyn, {Igor V.} and Carlson, {Robert M.}",

year = "2001",

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doi = "10.1021/ol016338v",

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T1 - A novel catalytic pathway for perfluoroacyl peroxide synthesis

AU - Krasutsky, Pavel A.

AU - Kolomitsyn, Igor V.

AU - Carlson, Robert M.

PY - 2001/9/20

Y1 - 2001/9/20

N2 - matrix presented A new catalytic method for synthesis of bis(perfluoroacyl) peroxides (BPFAP) was elaborated by using hydrogen peroxide and perfluoroacyl anhydrides. The desired BPFAP were formed quantitatively in situ when perfluoroacyl anhydride was mixed with hydrogen peroxide (ratio ≥ 2:1) in the presence of a catalytic amount of the carboxylate RfCOO- M+. The essentially irreversible character of this process was shown experimentally and supported on the basis of DFT calculations. The synthesis of new acetyltrifluoroacetyl peroxides is also described.

AB - matrix presented A new catalytic method for synthesis of bis(perfluoroacyl) peroxides (BPFAP) was elaborated by using hydrogen peroxide and perfluoroacyl anhydrides. The desired BPFAP were formed quantitatively in situ when perfluoroacyl anhydride was mixed with hydrogen peroxide (ratio ≥ 2:1) in the presence of a catalytic amount of the carboxylate RfCOO- M+. The essentially irreversible character of this process was shown experimentally and supported on the basis of DFT calculations. The synthesis of new acetyltrifluoroacetyl peroxides is also described.

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DO - 10.1021/ol016338v

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SN - 1523-7060

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EP - 2999

JO - Organic Letters

JF - Organic Letters

IS - 19

ER -

A novel catalytic pathway for perfluoroacyl peroxide synthesis

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