A one-step transformation of aromatic aldehydes to nitriles, using S,S-Dimethylsulfurdiimide as iminating agent. Isolation of dithiatetrazocines as reaction intermediates.

Gunda I. Georg; Sarah A. Pfeifer; Manfred Haake

doi:10.1016/S0040-4039(00)94899-8

A one-step transformation of aromatic aldehydes to nitriles, using S,S-Dimethylsulfurdiimide as iminating agent. Isolation of dithiatetrazocines as reaction intermediates.

Gunda I. Georg, Sarah A. Pfeifer, Manfred Haake

Medicinal Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

S,S-Dimethylsulfurdiimide is explored as a novel and effective reagent for the direct synthesis of aromatic nitriles from aldehydes. A novel eight-membered heterocycle is isolated as a reaction intermediate and a mechanism for this reaction is discussed.

Original language	English (US)
Pages (from-to)	2739-2742
Number of pages	4
Journal	Tetrahedron Letters
Volume	26
Issue number	23
DOIs	https://doi.org/10.1016/S0040-4039(00)94899-8
State	Published - 1985

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title = "A one-step transformation of aromatic aldehydes to nitriles, using S,S-Dimethylsulfurdiimide as iminating agent. Isolation of dithiatetrazocines as reaction intermediates.",

abstract = "S,S-Dimethylsulfurdiimide is explored as a novel and effective reagent for the direct synthesis of aromatic nitriles from aldehydes. A novel eight-membered heterocycle is isolated as a reaction intermediate and a mechanism for this reaction is discussed.",

author = "Georg, {Gunda I.} and Pfeifer, {Sarah A.} and Manfred Haake",

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language = "English (US)",

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T1 - A one-step transformation of aromatic aldehydes to nitriles, using S,S-Dimethylsulfurdiimide as iminating agent. Isolation of dithiatetrazocines as reaction intermediates.

AU - Georg, Gunda I.

AU - Pfeifer, Sarah A.

AU - Haake, Manfred

PY - 1985

Y1 - 1985

N2 - S,S-Dimethylsulfurdiimide is explored as a novel and effective reagent for the direct synthesis of aromatic nitriles from aldehydes. A novel eight-membered heterocycle is isolated as a reaction intermediate and a mechanism for this reaction is discussed.

AB - S,S-Dimethylsulfurdiimide is explored as a novel and effective reagent for the direct synthesis of aromatic nitriles from aldehydes. A novel eight-membered heterocycle is isolated as a reaction intermediate and a mechanism for this reaction is discussed.

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U2 - 10.1016/S0040-4039(00)94899-8

DO - 10.1016/S0040-4039(00)94899-8

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SN - 0040-4039

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JO - Tetrahedron Letters

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IS - 23

ER -

A one-step transformation of aromatic aldehydes to nitriles, using S,S-Dimethylsulfurdiimide as iminating agent. Isolation of dithiatetrazocines as reaction intermediates.

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