Abstract
The rate constant of the CH3O2 + NO gas-phase reaction was measured over the temperature range 199-429 K using chemical ionization mass spectrometry detection of the CH3O2 reactant. The temperature-dependent expression for the rate constant was determined to be k(T) = (2.8 ± 0.5) × 10-12 exp{(285 ± 60)/T} cm3 molecule-1 s-1. The 298 K rate constant, k = (7.5 ± 1.3) × 10-12 cm3 molecule-1 s-1, agrees well with previous results.
Original language | English (US) |
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Pages (from-to) | 12829-12834 |
Number of pages | 6 |
Journal | Journal of Physical Chemistry |
Volume | 99 |
Issue number | 34 |
DOIs | |
State | Published - Jan 1 1995 |
Externally published | Yes |