A tosylimido analogue of a nonheme oxoiron(IV) complex

Eric J. Klinker; Timothy A. Jackson; Michael P. Jensen; Audria Stubna; Gergely Juhász; Emile L. Bominaar; Eckard Münck; Lawrence Que

doi:10.1002/anie.200602799

A tosylimido analogue of a nonheme oxoiron(IV) complex

Eric J. Klinker, Timothy A. Jackson, Michael P. Jensen, Audria Stubna, Gergely Juhász, Emile L. Bominaar, Eckard Münck, Lawrence Que

Chemistry (Twin Cities)

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102 Scopus citations

Abstract

(Figure Presented) High-valent versatility: N4Py is a versatile pentadentate ligand demonstrated to stabilize both high-valent oxo and imido compounds. The [Fe^IV(NTs)(N4Py)]²⁺ complex (see DFT-optimized structure) has been characterized spectroscopically and formulated as having an S=1 iron(IV) center with an Fe=N bond (1.73 Å) that is longer than the Fe=O bond of its oxo analogue (1.65 Å).

Original language	English (US)
Pages (from-to)	7394-7397
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	44
DOIs	https://doi.org/10.1002/anie.200602799
State	Published - Nov 13 2006

Keywords

Bioinorganic chemistry
Density functional calculations
Imido ligands
Iron
Mössbauer spectroscopy

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title = "A tosylimido analogue of a nonheme oxoiron(IV) complex",

abstract = "(Figure Presented) High-valent versatility: N4Py is a versatile pentadentate ligand demonstrated to stabilize both high-valent oxo and imido compounds. The [FeIV(NTs)(N4Py)]2+ complex (see DFT-optimized structure) has been characterized spectroscopically and formulated as having an S=1 iron(IV) center with an Fe=N bond (1.73 {\AA}) that is longer than the Fe=O bond of its oxo analogue (1.65 {\AA}).",

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T1 - A tosylimido analogue of a nonheme oxoiron(IV) complex

AU - Klinker, Eric J.

AU - Jackson, Timothy A.

AU - Jensen, Michael P.

AU - Stubna, Audria

AU - Juhász, Gergely

AU - Bominaar, Emile L.

AU - Münck, Eckard

AU - Que, Lawrence

PY - 2006/11/13

Y1 - 2006/11/13

N2 - (Figure Presented) High-valent versatility: N4Py is a versatile pentadentate ligand demonstrated to stabilize both high-valent oxo and imido compounds. The [FeIV(NTs)(N4Py)]2+ complex (see DFT-optimized structure) has been characterized spectroscopically and formulated as having an S=1 iron(IV) center with an Fe=N bond (1.73 Å) that is longer than the Fe=O bond of its oxo analogue (1.65 Å).

AB - (Figure Presented) High-valent versatility: N4Py is a versatile pentadentate ligand demonstrated to stabilize both high-valent oxo and imido compounds. The [FeIV(NTs)(N4Py)]2+ complex (see DFT-optimized structure) has been characterized spectroscopically and formulated as having an S=1 iron(IV) center with an Fe=N bond (1.73 Å) that is longer than the Fe=O bond of its oxo analogue (1.65 Å).

KW - Bioinorganic chemistry

KW - Density functional calculations

KW - Imido ligands

KW - Iron

KW - Mössbauer spectroscopy

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A tosylimido analogue of a nonheme oxoiron(IV) complex

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