A tosylimido analogue of a nonheme oxoiron(IV) complex

Eric J. Klinker, Timothy A. Jackson, Michael P. Jensen, Audria Stubna, Gergely Juhász, Emile L. Bominaar, Eckard Münck, Lawrence Que

Research output: Contribution to journalArticlepeer-review

78 Scopus citations

Abstract

(Figure Presented) High-valent versatility: N4Py is a versatile pentadentate ligand demonstrated to stabilize both high-valent oxo and imido compounds. The [FeIV(NTs)(N4Py)]2+ complex (see DFT-optimized structure) has been characterized spectroscopically and formulated as having an S=1 iron(IV) center with an Fe=N bond (1.73 Å) that is longer than the Fe=O bond of its oxo analogue (1.65 Å).

Original languageEnglish (US)
Pages (from-to)7394-7397
Number of pages4
JournalAngewandte Chemie - International Edition
Volume45
Issue number44
DOIs
StatePublished - Nov 13 2006

Keywords

  • Bioinorganic chemistry
  • Density functional calculations
  • Imido ligands
  • Iron
  • Mössbauer spectroscopy

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