Access to the superstrong segregation regime with nonionic ABC copolymers

Timothy P. Lodge; Marc A. Hillmyer; Zhilian Zhou; Yeshayahu Talmon

doi:10.1021/ma048708b

Access to the superstrong segregation regime with nonionic ABC copolymers

Timothy P. Lodge, Marc A. Hillmyer, Zhilian Zhou, Yeshayahu Talmon

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

94 Scopus citations

Abstract

The access to the superstrong segregation regime (SSSR) with nonionic, flexible coil block copolymers, by use of three-monomers ABC triblock copolymers was discussed. An access to the SSSR consisted of a water soluble poly(ethylene oxide) (O) block, hydrocarbon, polystyrene (S) and a fluorppolymer (F). A linear OSB triblock prepared by controlled anionic polymerization, with block molecular weights of 13200 (N _o=300),4700 (N _s=45) and 1300 (N _b=24. It was observed that a new domain of block copolymers phase behavior, the superstrong segregation regime was accessed in a controled fashion with nonionic triblock copolumers.

Original language	English (US)
Pages (from-to)	6680-6682
Number of pages	3
Journal	Macromolecules
Volume	37
Issue number	18
DOIs	https://doi.org/10.1021/ma048708b
State	Published - Sep 7 2004

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abstract = "The access to the superstrong segregation regime (SSSR) with nonionic, flexible coil block copolymers, by use of three-monomers ABC triblock copolymers was discussed. An access to the SSSR consisted of a water soluble poly(ethylene oxide) (O) block, hydrocarbon, polystyrene (S) and a fluorppolymer (F). A linear OSB triblock prepared by controlled anionic polymerization, with block molecular weights of 13200 (N o=300),4700 (N s=45) and 1300 (N b=24. It was observed that a new domain of block copolymers phase behavior, the superstrong segregation regime was accessed in a controled fashion with nonionic triblock copolumers.",

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AB - The access to the superstrong segregation regime (SSSR) with nonionic, flexible coil block copolymers, by use of three-monomers ABC triblock copolymers was discussed. An access to the SSSR consisted of a water soluble poly(ethylene oxide) (O) block, hydrocarbon, polystyrene (S) and a fluorppolymer (F). A linear OSB triblock prepared by controlled anionic polymerization, with block molecular weights of 13200 (N o=300),4700 (N s=45) and 1300 (N b=24. It was observed that a new domain of block copolymers phase behavior, the superstrong segregation regime was accessed in a controled fashion with nonionic triblock copolumers.

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Access to the superstrong segregation regime with nonionic ABC copolymers

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