Alkane Functionalization at Nonheme Iron Centers. Stoichiometric Transfer of Metal-Bound Ligands to Alkane

Engineering & Materials Science

• Cyclohexane 96%
• Ligands 88%
• Amines 78%
• Paraffins 76%
• Iron 59%
• Catalysts 56%
• Biosynthesis 52%
• Catalyst selectivity 48%
• Oxidants 42%
• Crystal structure 42%
• Metals 42%
• Nuclear magnetic resonance 39%
• Sulfides 38%
• Enzymes 38%
• Electrons 33%
• Hydrogen 26%
• Temperature 13%

Chemical Compounds

• Alkyl Hydroperoxide 99%
• Haloalkane 63%
• Alkane 56%
• Halide 50%
• Cyclohexane 39%
• Tris 37%
• Isopenicillin N 36%
• Thiazolidine 30%
• Ligand 29%
• Dimethyl Sulfide 29%
• Amine 28%
• Adamantane 27%
• Visible Spectrum 25%
• Penicillin 25%
• Ring Formation 23%
• Hydroperoxide 22%
• Alkyl Group 21%
• Transfer Reaction 20%
• NMR Spectrum 19%
• Biosynthesis 18%
• Catalyst 18%
• Reaction Yield 17%
• Ambient Reaction Temperature 12%
• Hydrogen 11%
• Crystal Structure 11%
• Amount 9%

Medicine & Life Sciences

• Alkanes 100%
• perchlorate 74%
• Hydrogen Peroxide 66%
• Metals 57%
• Iron 55%
• Cyclohexane 51%
• Ligands 47%
• tris(2-pyridylmethyl)amine 41%
• 2,6-di-tert-butylphenol 34%
• penicillin N 32%
• dimethyl sulfide 29%
• Thiazolidines 28%
• Adamantane 27%
• Hydrogen 19%
• Dimethyl Sulfoxide 18%
• Amines 17%
• Oxidants 17%
• Penicillins 16%
• Electrons 13%
• Temperature 11%
• Enzymes 9%