Alkyne Insertion Reactions of Metal-Carbenes Derived from Enynyl a-Diazo Ketones [RCN2COCR2CH2C^C(CH2)n2CH=CH2]

Thomas R Hoye, Christopher J. Dinsmore, Douglas S. Johnson, Paul F. Korkowski

Research output: Contribution to journalArticlepeer-review

86 Scopus citations

Abstract

: The title substrates react with a variety of metal catalysts to give metal-dependent product arrays (including tricyclic cyclopropanes and others formally arising from the vinylogous a-keto carbene 3.

Original languageEnglish (US)
Pages (from-to)4518-4520
Number of pages3
JournalJournal of Organic Chemistry
Volume55
Issue number15
DOIs
StatePublished - Jan 1 1990

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