An expeditious coumarin synthesis via a "Pseudocycloaddition" between salicylaldehydes and ketene

Sosale Chandrasekhar; Honnaiah Vijay Kumar

doi:10.1080/00397911.2014.960938

An expeditious coumarin synthesis via a "Pseudocycloaddition" between salicylaldehydes and ketene

Sosale Chandrasekhar, Honnaiah Vijay Kumar

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A variety of salicylaldehydes effected tandem nucleophilic addition onto ketene, leading to corresponding coumarins in good yields under mild conditions. This "pseudocycloaddition" represents a very mild variant of the historic Perkin synthesis of coumarin (which remains of key interest in both perfumery and several emerging areas).

Original language	English (US)
Pages (from-to)	232-235
Number of pages	4
Journal	Synthetic Communications
Volume	45
Issue number	2
DOIs	https://doi.org/10.1080/00397911.2014.960938
State	Published - Jan 17 2015

Bibliographical note

Funding Information:
We are grateful to University Grants Commission (New Delhi) for generous financial support to H. V. K.

Publisher Copyright:
© 2015 Taylor & Francis Group, LLC.

Copyright:
Copyright 2015 Elsevier B.V., All rights reserved.

Keywords

Coumarin
Perkin synthesis
quinodimethane

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10.1080/00397911.2014.960938

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AU - Chandrasekhar, Sosale

AU - Kumar, Honnaiah Vijay

N1 - Funding Information: We are grateful to University Grants Commission (New Delhi) for generous financial support to H. V. K. Publisher Copyright: © 2015 Taylor & Francis Group, LLC. Copyright: Copyright 2015 Elsevier B.V., All rights reserved.

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N2 - A variety of salicylaldehydes effected tandem nucleophilic addition onto ketene, leading to corresponding coumarins in good yields under mild conditions. This "pseudocycloaddition" represents a very mild variant of the historic Perkin synthesis of coumarin (which remains of key interest in both perfumery and several emerging areas).

AB - A variety of salicylaldehydes effected tandem nucleophilic addition onto ketene, leading to corresponding coumarins in good yields under mild conditions. This "pseudocycloaddition" represents a very mild variant of the historic Perkin synthesis of coumarin (which remains of key interest in both perfumery and several emerging areas).

KW - Coumarin

KW - Perkin synthesis

KW - quinodimethane

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ER -

An expeditious coumarin synthesis via a "Pseudocycloaddition" between salicylaldehydes and ketene

Abstract

Bibliographical note

Keywords

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