An inverted and more oxidizing isomer of [FeIV(O)(tmc)- (NCCH3)]2+

Kallol Ray; Jason England; Adam T. Fiedler; Marlène Martinho; Eckard Münck; Lawrence Que

doi:10.1002/anie.200802219

An inverted and more oxidizing isomer of [Fe^IV(O)(tmc)- (NCCH₃)]²⁺

Kallol Ray, Jason England, Adam T. Fiedler, Marlène Martinho, Eckard Münck, Lawrence Que

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

(Chemical Equation Presented) Oxoferryl gymnastics: The oxo and CH ₃CN ligands in 1-NCCH₃ can swap positions in the presence of iodosobenzene and tetrafluoroborate anion leading to the generation of a more reactive isomer 2. This conversion is proposed to take place via an activated Fe^IV unit (1a) or a transient dioxoiron(VI) species (1b).

Original language	English (US)
Pages (from-to)	8068-8071
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	42
DOIs	https://doi.org/10.1002/anie.200802219
State	Published - Oct 6 2008

Keywords

Bioinorganic chemistry
Coordination modes
Cyclam
High-valent compounds
Nonheme iron complexes

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10.1002/anie.200802219

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AU - Fiedler, Adam T.

AU - Martinho, Marlène

AU - Münck, Eckard

AU - Que, Lawrence

PY - 2008/10/6

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KW - Coordination modes

KW - Cyclam

KW - High-valent compounds

KW - Nonheme iron complexes

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