An unusual rearrangement, and further transformations, in the chlorination of alkoxythiocarbonylsulfenyl substrates

George Barany

doi:10.1016/S0040-4039(00)94172-8

An unusual rearrangement, and further transformations, in the chlorination of alkoxythiocarbonylsulfenyl substrates

George Barany

Chemistry (Twin Cities)

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Abstract

Treatment of alkoxythiocarbonylsulfenyl substrates with one equiv. of sulfuryl chloride, expected to provide alkoxychlorothiochloromethylsulfenyl derivatives, gave directly alkoxydichloromethyldisulfanyl products via a rapid intramolecular rearrangement.

Original language	English (US)
Pages (from-to)	5683-5686
Number of pages	4
Journal	Tetrahedron Letters
Volume	24
Issue number	51
DOIs	https://doi.org/10.1016/S0040-4039(00)94172-8
State	Published - 1983

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title = "An unusual rearrangement, and further transformations, in the chlorination of alkoxythiocarbonylsulfenyl substrates",

abstract = "Treatment of alkoxythiocarbonylsulfenyl substrates with one equiv. of sulfuryl chloride, expected to provide alkoxychlorothiochloromethylsulfenyl derivatives, gave directly alkoxydichloromethyldisulfanyl products via a rapid intramolecular rearrangement.",

author = "George Barany",

year = "1983",

doi = "10.1016/S0040-4039(00)94172-8",

language = "English (US)",

volume = "24",

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journal = "Tetrahedron Letters",

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number = "51",

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T1 - An unusual rearrangement, and further transformations, in the chlorination of alkoxythiocarbonylsulfenyl substrates

AU - Barany, George

PY - 1983

Y1 - 1983

N2 - Treatment of alkoxythiocarbonylsulfenyl substrates with one equiv. of sulfuryl chloride, expected to provide alkoxychlorothiochloromethylsulfenyl derivatives, gave directly alkoxydichloromethyldisulfanyl products via a rapid intramolecular rearrangement.

AB - Treatment of alkoxythiocarbonylsulfenyl substrates with one equiv. of sulfuryl chloride, expected to provide alkoxychlorothiochloromethylsulfenyl derivatives, gave directly alkoxydichloromethyldisulfanyl products via a rapid intramolecular rearrangement.

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U2 - 10.1016/S0040-4039(00)94172-8

DO - 10.1016/S0040-4039(00)94172-8

M3 - Article

AN - SCOPUS:49049125026

SN - 0040-4039

VL - 24

SP - 5683

EP - 5686

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 51

ER -

An unusual rearrangement, and further transformations, in the chlorination of alkoxythiocarbonylsulfenyl substrates

Abstract

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