Analysis of the traveling heater method for the growth of cadmium telluride

Jeffrey H. Peterson, Michael Fiederle, Jeffrey J. Derby

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

We discuss the development and implementation of a comprehensive mathematical model for the traveling heater method (THM) that is formulated to realistically represent the interactions of heat and species transport, fluid flow, and interfacial dissolution and growth under conditions of local thermodynamic equilibrium and steady-state growth. We examine the complicated interactions among zone geometry, continuum transport, phase change, and fluid flow driven by buoyancy. Of particular interest and importance is the formation of flow structures in the liquid zone of the THM that arise from the same physical mechanism as lee waves in atmospheric flows and demonstrate the same characteristic Brunt–Väisälä scaling. We show that flow stagnation and reversal associated with lee-wave formation are responsible for the accumulation of tellurium and supercooled liquid near the growth interface, even when the lee-wave vortex is not readily apparent in the overall flow structure. The supercooled fluid is posited to result in morphological instability at growth rates far below the limit predicted by the classical criterion by Tiller et al. for constitutional supercooling.

Original languageEnglish (US)
Pages (from-to)45-58
Number of pages14
JournalJournal of Crystal Growth
Volume454
DOIs
StatePublished - Nov 15 2016

Bibliographical note

Funding Information:
This material is based upon work supported in part by the Minnesota Supercomputer Institute and the U.S. National Science Foundation , Materials World Network: Cooperative Activity in Materials Research between US Investigators and their Counterparts Abroad (MWN), under NSF DMR-10007885 . We acknowledge the significant input of Andrew Yeckel, who supported this work though code development. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the National Science Foundation.

Keywords

  • A1. Computer simulation
  • A1. Convection
  • A1. Mass transfer
  • A2. Traveling heater method growth
  • A2. Traveling solvent zone growth
  • B2. Semiconducting II-VI materials
  • Heat transfer

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