Biochar-driven simplification of the compositions of cellulose-pyrolysis-derived biocrude oil coupled with the promotion of hydrogen generation

Chenxi Wang; Hanwu Lei; Rongge Zou; Moriko Qian; Wendy Mateo; Xiaona Lin; Roger Ruan

doi:10.1016/j.biortech.2021.125251

Biochar-driven simplification of the compositions of cellulose-pyrolysis-derived biocrude oil coupled with the promotion of hydrogen generation

Chenxi Wang, Hanwu Lei, Rongge Zou, Moriko Qian, Wendy Mateo, Xiaona Lin, Roger Ruan

Bioproducts and Biosystems Engineering

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

The corn stover originated biochar was developed to catalyze and simplify the compositions of biocrude oil from cellulose pyrolysis. The generation of common species such as furans and (anhydro)-sugars in the biocrude oil from cellulose pyrolysis was weakened remarkably in the presence of biochars, while the formation of phenol and alkylphenols was enhanced. The formation of hydrogen was favored when the biochar was presented. For example at the temperature of 600 °C and biochar to cellulose ratio of 3, about 78 vol% of hydrogen was detected, increased from around 48 vol% for non-catalytic pyrolysis. Despite 10 cycles of reuse, the biochar remained a good activity towards promoting the generation of hydrogen and monomeric phenols. This work relates to a new access to simplify the compositions of biocrude oil and produce renewable hydrogen energy through the low-cost, simple, and highly stable biochar catalyst.

Original language	English (US)
Article number	125251
Journal	Bioresource Technology
Volume	334
DOIs	https://doi.org/10.1016/j.biortech.2021.125251
State	Published - Aug 2021

Bibliographical note

Funding Information:
This study was supported by the Agriculture and Food Research Initiative Competitive Grant no. 2016-67021-24533 and 2018-67009-27904 from the National Institute of Food and Agriculture, United States Department of Agriculture. We are grateful for the help from Dr. Aftab Ahamed with the GC/MS analysis in Bioproducts, Sciences, & Engineering Laboratory (BSEL). And we also acknowledge Dr. Valerie Lynch-Holm and Dr. Dan Mullendore in Franceschi Microscopy & Imaging Center (FMIC) at Washington State University involving the SEM in this work.

Funding Information:
This study was supported by the Agriculture and Food Research Initiative Competitive Grant no. 2016-67021-24533 and 2018-67009-27904 from the National Institute of Food and Agriculture, United States Department of Agriculture. We are grateful for the help from Dr. Aftab Ahamed with the GC/MS analysis in Bioproducts, Sciences, & Engineering Laboratory (BSEL). And we also acknowledge Dr. Valerie Lynch-Holm and Dr. Dan Mullendore in Franceschi Microscopy & Imaging Center (FMIC) at Washington State University involving the SEM in this work.

Publisher Copyright:
© 2021 Elsevier Ltd

Keywords

Biochar
Biocrude oil
Cellulose pyrolysis
Hydrogen
Monomeric phenols

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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title = "Biochar-driven simplification of the compositions of cellulose-pyrolysis-derived biocrude oil coupled with the promotion of hydrogen generation",

abstract = "The corn stover originated biochar was developed to catalyze and simplify the compositions of biocrude oil from cellulose pyrolysis. The generation of common species such as furans and (anhydro)-sugars in the biocrude oil from cellulose pyrolysis was weakened remarkably in the presence of biochars, while the formation of phenol and alkylphenols was enhanced. The formation of hydrogen was favored when the biochar was presented. For example at the temperature of 600 °C and biochar to cellulose ratio of 3, about 78 vol% of hydrogen was detected, increased from around 48 vol% for non-catalytic pyrolysis. Despite 10 cycles of reuse, the biochar remained a good activity towards promoting the generation of hydrogen and monomeric phenols. This work relates to a new access to simplify the compositions of biocrude oil and produce renewable hydrogen energy through the low-cost, simple, and highly stable biochar catalyst.",

keywords = "Biochar, Biocrude oil, Cellulose pyrolysis, Hydrogen, Monomeric phenols",

author = "Chenxi Wang and Hanwu Lei and Rongge Zou and Moriko Qian and Wendy Mateo and Xiaona Lin and Roger Ruan",

note = "Funding Information: This study was supported by the Agriculture and Food Research Initiative Competitive Grant no. 2016-67021-24533 and 2018-67009-27904 from the National Institute of Food and Agriculture, United States Department of Agriculture. We are grateful for the help from Dr. Aftab Ahamed with the GC/MS analysis in Bioproducts, Sciences, & Engineering Laboratory (BSEL). And we also acknowledge Dr. Valerie Lynch-Holm and Dr. Dan Mullendore in Franceschi Microscopy & Imaging Center (FMIC) at Washington State University involving the SEM in this work. Funding Information: This study was supported by the Agriculture and Food Research Initiative Competitive Grant no. 2016-67021-24533 and 2018-67009-27904 from the National Institute of Food and Agriculture, United States Department of Agriculture. We are grateful for the help from Dr. Aftab Ahamed with the GC/MS analysis in Bioproducts, Sciences, & Engineering Laboratory (BSEL). And we also acknowledge Dr. Valerie Lynch-Holm and Dr. Dan Mullendore in Franceschi Microscopy & Imaging Center (FMIC) at Washington State University involving the SEM in this work. Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd",

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AU - Qian, Moriko

AU - Mateo, Wendy

AU - Lin, Xiaona

AU - Ruan, Roger

N1 - Funding Information: This study was supported by the Agriculture and Food Research Initiative Competitive Grant no. 2016-67021-24533 and 2018-67009-27904 from the National Institute of Food and Agriculture, United States Department of Agriculture. We are grateful for the help from Dr. Aftab Ahamed with the GC/MS analysis in Bioproducts, Sciences, & Engineering Laboratory (BSEL). And we also acknowledge Dr. Valerie Lynch-Holm and Dr. Dan Mullendore in Franceschi Microscopy & Imaging Center (FMIC) at Washington State University involving the SEM in this work. Funding Information: This study was supported by the Agriculture and Food Research Initiative Competitive Grant no. 2016-67021-24533 and 2018-67009-27904 from the National Institute of Food and Agriculture, United States Department of Agriculture. We are grateful for the help from Dr. Aftab Ahamed with the GC/MS analysis in Bioproducts, Sciences, & Engineering Laboratory (BSEL). And we also acknowledge Dr. Valerie Lynch-Holm and Dr. Dan Mullendore in Franceschi Microscopy & Imaging Center (FMIC) at Washington State University involving the SEM in this work. Publisher Copyright: © 2021 Elsevier Ltd

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N2 - The corn stover originated biochar was developed to catalyze and simplify the compositions of biocrude oil from cellulose pyrolysis. The generation of common species such as furans and (anhydro)-sugars in the biocrude oil from cellulose pyrolysis was weakened remarkably in the presence of biochars, while the formation of phenol and alkylphenols was enhanced. The formation of hydrogen was favored when the biochar was presented. For example at the temperature of 600 °C and biochar to cellulose ratio of 3, about 78 vol% of hydrogen was detected, increased from around 48 vol% for non-catalytic pyrolysis. Despite 10 cycles of reuse, the biochar remained a good activity towards promoting the generation of hydrogen and monomeric phenols. This work relates to a new access to simplify the compositions of biocrude oil and produce renewable hydrogen energy through the low-cost, simple, and highly stable biochar catalyst.

AB - The corn stover originated biochar was developed to catalyze and simplify the compositions of biocrude oil from cellulose pyrolysis. The generation of common species such as furans and (anhydro)-sugars in the biocrude oil from cellulose pyrolysis was weakened remarkably in the presence of biochars, while the formation of phenol and alkylphenols was enhanced. The formation of hydrogen was favored when the biochar was presented. For example at the temperature of 600 °C and biochar to cellulose ratio of 3, about 78 vol% of hydrogen was detected, increased from around 48 vol% for non-catalytic pyrolysis. Despite 10 cycles of reuse, the biochar remained a good activity towards promoting the generation of hydrogen and monomeric phenols. This work relates to a new access to simplify the compositions of biocrude oil and produce renewable hydrogen energy through the low-cost, simple, and highly stable biochar catalyst.

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Biochar-driven simplification of the compositions of cellulose-pyrolysis-derived biocrude oil coupled with the promotion of hydrogen generation

Abstract

Bibliographical note

Keywords

UN SDGs

Access

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