Blue thermally activated delayed fluorescence from a biphenyl difluoroboron β-diketonate

Margaret L. Daly; Christopher A. Derosa; Caroline Kerr; William A. Morris; Cassandra L. Fraser

doi:10.1039/c6ra18374c

Blue thermally activated delayed fluorescence from a biphenyl difluoroboron β-diketonate

Margaret L. Daly, Christopher A. Derosa, Caroline Kerr, William A. Morris, Cassandra L. Fraser

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

Optical properties of biphenyl difluoroboron β-diketonates were studied in poly(lactic acid) (PLA) blends. Increased conjugation lowered the emission energy, decreased the singlet-triplet energy gap and yielded blue thermally activated delayed fluorescence (TADF). The properties of these biphenyl dyes may inform organic light emitting diode (OLED) and bioimaging agent design.

Original language	English (US)
Pages (from-to)	81631-81635
Number of pages	5
Journal	RSC Advances
Volume	6
Issue number	85
DOIs	https://doi.org/10.1039/c6ra18374c
State	Published - 2016
Externally published	Yes

Bibliographical note

Funding Information:
We thank the National Science Foundation (CHE-1213915), the National Institutes of Health (R01 CA167250) and UVA Cancer Center (P30 CA44579) for support for this work. We gratefully acknowledge the UVA Center for Undergraduate Excellence for Harrison Undergraduate Research Awards to M. D. and C. K. and the Beckman Scholars Program for a fellowship to C. K. We thank Prof. Carl O. Trindle for helpful discussions.

Publisher Copyright:
© 2016 The Royal Society of Chemistry.

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title = "Blue thermally activated delayed fluorescence from a biphenyl difluoroboron β-diketonate",

abstract = "Optical properties of biphenyl difluoroboron β-diketonates were studied in poly(lactic acid) (PLA) blends. Increased conjugation lowered the emission energy, decreased the singlet-triplet energy gap and yielded blue thermally activated delayed fluorescence (TADF). The properties of these biphenyl dyes may inform organic light emitting diode (OLED) and bioimaging agent design.",

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T1 - Blue thermally activated delayed fluorescence from a biphenyl difluoroboron β-diketonate

AU - Daly, Margaret L.

AU - Derosa, Christopher A.

AU - Kerr, Caroline

AU - Morris, William A.

AU - Fraser, Cassandra L.

N1 - Funding Information: We thank the National Science Foundation (CHE-1213915), the National Institutes of Health (R01 CA167250) and UVA Cancer Center (P30 CA44579) for support for this work. We gratefully acknowledge the UVA Center for Undergraduate Excellence for Harrison Undergraduate Research Awards to M. D. and C. K. and the Beckman Scholars Program for a fellowship to C. K. We thank Prof. Carl O. Trindle for helpful discussions. Publisher Copyright: © 2016 The Royal Society of Chemistry.

PY - 2016

Y1 - 2016

N2 - Optical properties of biphenyl difluoroboron β-diketonates were studied in poly(lactic acid) (PLA) blends. Increased conjugation lowered the emission energy, decreased the singlet-triplet energy gap and yielded blue thermally activated delayed fluorescence (TADF). The properties of these biphenyl dyes may inform organic light emitting diode (OLED) and bioimaging agent design.

AB - Optical properties of biphenyl difluoroboron β-diketonates were studied in poly(lactic acid) (PLA) blends. Increased conjugation lowered the emission energy, decreased the singlet-triplet energy gap and yielded blue thermally activated delayed fluorescence (TADF). The properties of these biphenyl dyes may inform organic light emitting diode (OLED) and bioimaging agent design.

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Blue thermally activated delayed fluorescence from a biphenyl difluoroboron β-diketonate

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