Boron-heck reaction of cyclic enaminones: Regioselective direct arylation via oxidative palladium(II) catalysis

Yong Wook Kim, Gunda I. Georg

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

An oxidative boron-Heck reaction of cyclic enaminones with arylboronic acids is reported. This protocol provides a regioselective arylation at the C6 position of cyclic enaminones. When an N-carbamylated cyclic enaminone was employed, a switch to a conjugate addition reaction occurred in the presence of acid.

Original languageEnglish (US)
Pages (from-to)1574-1577
Number of pages4
JournalOrganic Letters
Volume16
Issue number6
DOIs
StatePublished - Mar 21 2014

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