TY - JOUR
T1 - Calibration of the infrared molar absorption coefficients for H in olivine, clinopyroxene and rhyolitic glass by elastic recoil detection analysis
AU - Aubaud, Cyril
AU - Bureau, Hélène
AU - Raepsaet, Caroline
AU - Khodja, Hicham
AU - Withers, Anthony C.
AU - Hirschmann, Marc M.
AU - Bell, David R.
PY - 2009/5
Y1 - 2009/5
N2 - We use a nuclear microbeam technique (Elastic Recoil Detection Analysis or ERDA) to measure the H content in 2 rhyolitic glasses, 4 olivines, 4 orthopyroxenes, and 7 clinopyroxenes. These samples have been characterized previously for their OH absorption spectra by infrared (FTIR) spectroscopy. We use ERDA and FTIR data to calibrate the infrared molar absorption coefficients. The blank level of the ERDA method is 102±81ppm H2O, too great for the analysis of many natural nominally anhydrousminerals (NAMs) fromthe uppermantle, but applicable to H-rich glasses, natural and synthetic NAMs. Calibration of the molar absorption coefficient ε with the ERDA results gives 95±8 l mol-1 cm-1 for rhyolitic glasses (peak height), 34,515±7050 l mol-1 cm-2 for olivine and 46,103±5300 l mol-1 cm-2 for clinopyroxene (integrated area). The olivine calibration of the present study is intermediate between that of Bell et al. [Bell, D.R., Rossman,G.R.,Maldener, J.,Endisch,D. and Rauch, F.,2003.Hydroxide in olivine: a quantitative determination of the absolute amount and calibration of the IR spectrum. Journal of Geophysical Research, 108(B2). doi:10.1029/2001JB000679] and that of Libowitzky and Rossman [Libowitzky, E. and Rossman, G.R., 1997. An IR absorption calibration for water in minerals. American Mineralogist, 82: 1111-1115]. For clinopyroxene, the best agreement with the ERDA data is obtained for the Libowitzky and Rossman [Libowitzky, E. and Rossman, G.R., 1997. An IR absorption calibration forwater in minerals. AmericanMineralogist, 82: 1111-1115] calibration (5% lower than the ERDA data). The present calibration also confirms that the Paterson [Paterson, M.S., 1982. The determination of hydroxyl by infrared absorption inquartz, silicate glasses and similarmaterials. Bulletin deMineralogie,105: 20-29] calibration systematically underestimates the OH content in olivine.
AB - We use a nuclear microbeam technique (Elastic Recoil Detection Analysis or ERDA) to measure the H content in 2 rhyolitic glasses, 4 olivines, 4 orthopyroxenes, and 7 clinopyroxenes. These samples have been characterized previously for their OH absorption spectra by infrared (FTIR) spectroscopy. We use ERDA and FTIR data to calibrate the infrared molar absorption coefficients. The blank level of the ERDA method is 102±81ppm H2O, too great for the analysis of many natural nominally anhydrousminerals (NAMs) fromthe uppermantle, but applicable to H-rich glasses, natural and synthetic NAMs. Calibration of the molar absorption coefficient ε with the ERDA results gives 95±8 l mol-1 cm-1 for rhyolitic glasses (peak height), 34,515±7050 l mol-1 cm-2 for olivine and 46,103±5300 l mol-1 cm-2 for clinopyroxene (integrated area). The olivine calibration of the present study is intermediate between that of Bell et al. [Bell, D.R., Rossman,G.R.,Maldener, J.,Endisch,D. and Rauch, F.,2003.Hydroxide in olivine: a quantitative determination of the absolute amount and calibration of the IR spectrum. Journal of Geophysical Research, 108(B2). doi:10.1029/2001JB000679] and that of Libowitzky and Rossman [Libowitzky, E. and Rossman, G.R., 1997. An IR absorption calibration for water in minerals. American Mineralogist, 82: 1111-1115]. For clinopyroxene, the best agreement with the ERDA data is obtained for the Libowitzky and Rossman [Libowitzky, E. and Rossman, G.R., 1997. An IR absorption calibration forwater in minerals. AmericanMineralogist, 82: 1111-1115] calibration (5% lower than the ERDA data). The present calibration also confirms that the Paterson [Paterson, M.S., 1982. The determination of hydroxyl by infrared absorption inquartz, silicate glasses and similarmaterials. Bulletin deMineralogie,105: 20-29] calibration systematically underestimates the OH content in olivine.
KW - Detection analysis
KW - Elastic recoil
KW - Infrared spectroscopy
KW - Nominally anhydrous minerals
KW - Volcanic glasses
KW - Water
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U2 - 10.1016/j.chemgeo.2009.01.001
DO - 10.1016/j.chemgeo.2009.01.001
M3 - Article
AN - SCOPUS:77955918043
SN - 0009-2541
VL - 262
SP - 78
EP - 86
JO - Chemical Geology
JF - Chemical Geology
IS - 1-2
ER -