Carbonylative enantioselective meso-desymmetrization of cis-epoxides to trans-β-lactones: Effect of salen-ligand electronic variation on enantioselectivity

Michael Mulzer; Jessica R. Lamb; Zachary Nelson; Geoffrey W. Coates

doi:10.1039/c4cc04397a

Carbonylative enantioselective meso-desymmetrization of cis-epoxides to trans-β-lactones: Effect of salen-ligand electronic variation on enantioselectivity

Michael Mulzer, Jessica R. Lamb, Zachary Nelson, Geoffrey W. Coates

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The deprotection of a common precursor moiety in dithiolene chemistry was discovered to be fully reversible, which, besides being relevant for researchers working in very different fields with these non-innocent ligand systems, may even have an impact on CO₂ housekeeping, as the deprotected ligand acts as an efficient trap.

Original language	English (US)
Pages (from-to)	9842-9845
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	69
DOIs	https://doi.org/10.1039/c4cc04397a
State	Published - Jul 31 2014
Externally published	Yes

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Carbonylative enantioselective meso-desymmetrization of cis-epoxides to trans-β-lactones: Effect of salen-ligand electronic variation on enantioselectivity

Abstract

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