Cationic cyclization of styrene-butadiene rubber

Chaoyang Wang, Xuepin Huang, Jihua Yang

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

Controlled cyclization of styrene-butadiene rubber (SBR) was achieved with the aid of cationic catalyst system based on diethylaluminium chloride (AlEt2Cl) and benzyl chloride (C6H5CH2Cl) and by working in xylene solution at high temperature (T > 100°C). The main parameters of the cyclization process were investigated. Elastomers with low intrinsic viscosity, ready solubility, free gel were obtained. The products were characterized with IR 1H-NMR, DSC, GPC. The polycyclic structure was determined.

Original languageEnglish (US)
Pages (from-to)1895-1899
Number of pages5
JournalEuropean Polymer Journal
Volume37
Issue number9
DOIs
StatePublished - Sep 2001

Keywords

  • Benzyl chloride
  • Cationic cyclization
  • Diethylaluminum chloride
  • Styrene-butadiene rubber

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