Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

David P. De Sousa, Jennifer O. Bigelow, Jonas Sundberg, Lawrence Que, Christine J. McKenzie

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

A Cr(iv)η2-peroxo complex crystallizes from 33% aqueous H2O2. The complex is a likely intermediate in catalytic disproportionation of H2O2 proposed to occur through a single metal site mechanism in solution-and solid state.

Original languageEnglish (US)
Pages (from-to)2802-2805
Number of pages4
JournalChemical Communications
Volume51
Issue number14
DOIs
StatePublished - Feb 18 2015

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry 2015.

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