Characterizationf of autoxidation products of retinoic acid

A. R. Oyler; M. G. Motto; R. E. Naldi; K. L. Facchine; P. F. Hamburg; D. J. Burinsky; R. Dunphy; M. L. Cotter

doi:10.1016/S0040-4020(01)85785-9

Characterizationf of autoxidation products of retinoic acid

A. R. Oyler, M. G. Motto, R. E. Naldi, K. L. Facchine, P. F. Hamburg, D. J. Burinsky, R. Dunphy, M. L. Cotter

Chemistry & Biochemistry

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Abstract

Retinoic acid underwent autoxidation in 90% ethanol at 25-85.5 °C to give epoxides, dioxetanes, an endoperoxide, and double-bond cleavage products. The majority of these products appear to have resulted from the initial direct oxidation of the olefinic carbons rather than from the expected allylic α oxidation process.

Original language	English (US)
Pages (from-to)	7679-7694
Number of pages	16
Journal	Tetrahedron
Volume	45
Issue number	24
DOIs	https://doi.org/10.1016/S0040-4020(01)85785-9
State	Published - 1989

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title = "Characterizationf of autoxidation products of retinoic acid",

abstract = "Retinoic acid underwent autoxidation in 90% ethanol at 25-85.5 °C to give epoxides, dioxetanes, an endoperoxide, and double-bond cleavage products. The majority of these products appear to have resulted from the initial direct oxidation of the olefinic carbons rather than from the expected allylic α oxidation process.",

author = "Oyler, {A. R.} and Motto, {M. G.} and Naldi, {R. E.} and Facchine, {K. L.} and Hamburg, {P. F.} and Burinsky, {D. J.} and R. Dunphy and Cotter, {M. L.}",

year = "1989",

doi = "10.1016/S0040-4020(01)85785-9",

language = "English (US)",

volume = "45",

pages = "7679--7694",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Limited",

number = "24",

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TY - JOUR

T1 - Characterizationf of autoxidation products of retinoic acid

AU - Oyler, A. R.

AU - Motto, M. G.

AU - Naldi, R. E.

AU - Facchine, K. L.

AU - Hamburg, P. F.

AU - Burinsky, D. J.

AU - Dunphy, R.

AU - Cotter, M. L.

PY - 1989

Y1 - 1989

N2 - Retinoic acid underwent autoxidation in 90% ethanol at 25-85.5 °C to give epoxides, dioxetanes, an endoperoxide, and double-bond cleavage products. The majority of these products appear to have resulted from the initial direct oxidation of the olefinic carbons rather than from the expected allylic α oxidation process.

AB - Retinoic acid underwent autoxidation in 90% ethanol at 25-85.5 °C to give epoxides, dioxetanes, an endoperoxide, and double-bond cleavage products. The majority of these products appear to have resulted from the initial direct oxidation of the olefinic carbons rather than from the expected allylic α oxidation process.

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U2 - 10.1016/S0040-4020(01)85785-9

DO - 10.1016/S0040-4020(01)85785-9

M3 - Article

AN - SCOPUS:0024851317

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VL - 45

SP - 7679

EP - 7694

JO - Tetrahedron

JF - Tetrahedron

IS - 24

ER -

Characterizationf of autoxidation products of retinoic acid

Abstract

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