TY - JOUR
T1 - Chemical Vapor Deposition of Ruthenium and Osmium Thin Films Using (Hexafluoro-2-butyne)tetracarbonylruthenium and -osmium
AU - Senzaki, Yoshihide
AU - Gladfelter, Wayne L.
AU - McCormick, Fred B.
PY - 1993/1/1
Y1 - 1993/1/1
N2 - The known mononuclear ruthenium complex Ru(hfb)(CO)4, where hfb stands for hexafluoro-2-butyne, has a vapor pressure of 1.5 Torr at 25 °C and forms reflective ruthenium thin films by chemical vapor deposition (CVD) using H2 carrier gas with a growth rate of 21 nm/min at 500 °C. The resistivity of a ruthenium film having a grain size of 60 nm was 22 µΩ cm. Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD) analyses indicated that the films were pure, polycrystalline ruthenium (<1% C, 0, or F). Scanning electron microscopy and XRD analyses revealed that the deposition temperature and the presence of H2 gas affect the microstructure and the resistivity of the films. Os(hfb)-(CO)4 afforded polycrystalline osmium thin films using H2 as a carrier gas. A growth rate of 14 nm/min, a resistivity of 81 µΩ cm, and a grain size of 20 nm were found for depositions conducted at 600 °C. XPS analysis indicated that the film consists of 84% Os, 7% O, and 9% C. The new dinuclear metal complexes M2[µ-η1:η1:η4:-C4(CF3)4] (CO)6 (M = Ru, Os) were formed from M(hfb) (CO)4 during the CVD processes conducted in the absence of H2 gas at the temperature range 150–300 °C.
AB - The known mononuclear ruthenium complex Ru(hfb)(CO)4, where hfb stands for hexafluoro-2-butyne, has a vapor pressure of 1.5 Torr at 25 °C and forms reflective ruthenium thin films by chemical vapor deposition (CVD) using H2 carrier gas with a growth rate of 21 nm/min at 500 °C. The resistivity of a ruthenium film having a grain size of 60 nm was 22 µΩ cm. Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD) analyses indicated that the films were pure, polycrystalline ruthenium (<1% C, 0, or F). Scanning electron microscopy and XRD analyses revealed that the deposition temperature and the presence of H2 gas affect the microstructure and the resistivity of the films. Os(hfb)-(CO)4 afforded polycrystalline osmium thin films using H2 as a carrier gas. A growth rate of 14 nm/min, a resistivity of 81 µΩ cm, and a grain size of 20 nm were found for depositions conducted at 600 °C. XPS analysis indicated that the film consists of 84% Os, 7% O, and 9% C. The new dinuclear metal complexes M2[µ-η1:η1:η4:-C4(CF3)4] (CO)6 (M = Ru, Os) were formed from M(hfb) (CO)4 during the CVD processes conducted in the absence of H2 gas at the temperature range 150–300 °C.
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U2 - 10.1021/cm00036a008
DO - 10.1021/cm00036a008
M3 - Article
AN - SCOPUS:0001573958
SN - 0897-4756
VL - 5
SP - 1715
EP - 1721
JO - Chemistry of Materials
JF - Chemistry of Materials
IS - 12
ER -