Copper selective adsorption with a microemulsion‐based resin

James H.‐K Yang, John H. Burban, Edward L Cussler Jr

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

Cross‐linked terpolymers of allyl acetylacetone, 2‐hydroxyethyl methacrylate, and ethylene glycol dimethacrylate were synthesized in the oil phase of a bicontinuous microemulsion stabilized with didodecyldimethylammonium bromide. The resulting material is porous, with a surface area of 58 m2/dry g. It selectively adsorbs copper, picking up 0.07 meq/dry g from a 0.1‐M solution. This is less than the total apparent capacity of 0.65 meq/dry g inferred from titration with base and much less than the amount in conventional, nonselective resins, which is typically 5 meq/dry g. Breakthrough curves in packed beds and across membranes of this material seem consistent with uptake controlled by chemical reaction compromised by dispersion. Nonporous membranes of this material do not show facilitated transport.

Original languageEnglish (US)
Pages (from-to)1165-1170
Number of pages6
JournalAIChE Journal
Volume41
Issue number5
DOIs
StatePublished - May 1995

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