Correlations between Magnetism and Structure in Dinuclear CuIIFeIII Complexes with Integer Spin EPR Signals

Theodore R. Holman, Kevin A. Andersen, Oren P. Anderson, Michael P. Hendrich, Carlos Juarez‐Garcia, Eckard Münck, Lawrence Que

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

The FeIII and the CuII‐atom in the complexes 1 and 2 shown below are antiferromagnetically and ferromagnetically coupled, respectively. This difference in the coupling interaction can be correlated with the orientation of the orbital at CuII responsible for the magnetism relative to the bridging phenolate O‐atom. L = 2 6‐bis[(bis(2‐pyridylmethyl)amino(methyl))]‐4‐methylphenol. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)921-923
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume29
Issue number8
DOIs
StatePublished - Aug 1990

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