Cyclodextrin nanosponges as effective gas carriers

Francesco Trotta, Roberta Cavalli, Katia Martina, Miriam Biasizzo, Jenny Vitillo, Silvia Bordiga, Pradeep Vavia, Khalid Ansari

Research output: Contribution to journalArticlepeer-review

55 Scopus citations

Abstract

Cyclodextrin based carbonate nanosponges were synthetized starting from native β-cylodextrin and active carbonyl compounds i.e. carbonildiimidazole. In this work they were used to form inclusion complexes with three different gases i.e. 1-methylcyclopropene, oxygen and carbon dioxide. The encapsulation of gases were proved by direct reaction to known adduct (1-methylcyclopropene), by gravimetric analysis (CO2) and by oxymeter (Oxygen). The complexetion of oxygen or carbon dioxide could be useful for many biomedical applications. In particular the oxygen-filled nanosponges could supply oxygen to the hypoxic tissues which are present in various deseases. 1-methylcyclopropene included in β-cyclodextrin nanosponges showed superior antiethylenic performances in long lasting cut flowers in comparison with marketed products.

Original languageEnglish (US)
Pages (from-to)189-194
Number of pages6
JournalJournal of Inclusion Phenomena and Macrocyclic Chemistry
Volume71
Issue number1-2
DOIs
StatePublished - Oct 2011

Bibliographical note

Copyright:
Copyright 2011 Elsevier B.V., All rights reserved.

Keywords

  • Cyclodextrin
  • Gas encapsulation
  • Inclusion compounds
  • Nanosponges

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