Derivatives of 2-iodoxybenzenesulfonic acid: New pseudocyclic hypervalent iodine reagents

Viktor Zhdankin; Rostyslav N. Goncharenko; Dmitry N. Litvinov; Alexey Y. Koposov

Derivatives of 2-iodoxybenzenesulfonic acid: New pseudocyclic hypervalent iodine reagents

Viktor Zhdankin, Rostyslav N. Goncharenko, Dmitry N. Litvinov, Alexey Y. Koposov

Chemistry & Biochemistry

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27 Scopus citations

Abstract

Amides and esters of 2-iodoxybenzenesulfonic acid were prepared by dimethyldioxirane oxidation of the respective monovalent iodine derivatives and isolated as stable, microcrystalline compounds. These new hypervalent iodine reagents with a pseudobenziodoxole structure are efficient oxidizers of alcohols, secondary amines and sulfides.

Original language	English (US)
Pages (from-to)	8-18
Number of pages	11
Journal	Arkivoc
Volume	2005
Issue number	4
State	Published - Sep 14 2004

Keywords

Hypervalent iodine
IBX
Oxidation
Pseudobenziodoxole

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AU - Litvinov, Dmitry N.

AU - Koposov, Alexey Y.

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AB - Amides and esters of 2-iodoxybenzenesulfonic acid were prepared by dimethyldioxirane oxidation of the respective monovalent iodine derivatives and isolated as stable, microcrystalline compounds. These new hypervalent iodine reagents with a pseudobenziodoxole structure are efficient oxidizers of alcohols, secondary amines and sulfides.

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Derivatives of 2-iodoxybenzenesulfonic acid: New pseudocyclic hypervalent iodine reagents

Abstract

Keywords

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