Designed Syntheses of Heterobimetallic Fulvalene Complexes

Mark A. Huffman, David A. Newman, Mats Tilset, William B. Tolman, K. Peter C. Vollhardt

Research output: Contribution to journalArticlepeer-review

37 Scopus citations

Abstract

Two synthetic strategies to the construction of heterobimetallic fulvalene (η55-C10H8) complexes are reported. The first is based on the previously described monometallic ring-slippage products of (η5:η5-C10H8)Mo2-(CO)8and (η5:η5-C10H8)Ru2(CO)4that undergo recomplexation with a variety of metal carbonyls. The second utilizes a potentially iterative synthetic organic strategy in which cyclopentadienyl anion is subjected to an alkano-ylation–ring closure sequence that assembles a new attached cyclopentadiene unit.

Original languageEnglish (US)
Pages (from-to)1926-1928
Number of pages3
JournalOrganometallics
Volume5
Issue number9
DOIs
StatePublished - Jan 1 1986

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