Designed Syntheses of Heterobimetallic Fulvalene Complexes

Mark A. Huffman; David A. Newman; Mats Tilset; William B. Tolman; K. Peter C. Vollhardt

doi:10.1021/om00140a038

Designed Syntheses of Heterobimetallic Fulvalene Complexes

Mark A. Huffman, David A. Newman, Mats Tilset, William B. Tolman, K. Peter C. Vollhardt

Chemistry (Twin Cities)

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Abstract

Two synthetic strategies to the construction of heterobimetallic fulvalene (η⁵:η⁵-C₁₀H₈) complexes are reported. The first is based on the previously described monometallic ring-slippage products of (η5:η5-C10H8)Mo₂-(CO)₈and (η⁵:η5-C10H8)Ru₂(CO)₄that undergo recomplexation with a variety of metal carbonyls. The second utilizes a potentially iterative synthetic organic strategy in which cyclopentadienyl anion is subjected to an alkano-ylation–ring closure sequence that assembles a new attached cyclopentadiene unit.

Original language	English (US)
Pages (from-to)	1926-1928
Number of pages	3
Journal	Organometallics
Volume	5
Issue number	9
DOIs	https://doi.org/10.1021/om00140a038
State	Published - Jan 1 1986

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title = "Designed Syntheses of Heterobimetallic Fulvalene Complexes",

abstract = "Two synthetic strategies to the construction of heterobimetallic fulvalene (η5:η5-C10H8) complexes are reported. The first is based on the previously described monometallic ring-slippage products of (η5:η5-C10H8)Mo2-(CO)8and (η5:η5-C10H8)Ru2(CO)4that undergo recomplexation with a variety of metal carbonyls. The second utilizes a potentially iterative synthetic organic strategy in which cyclopentadienyl anion is subjected to an alkano-ylation–ring closure sequence that assembles a new attached cyclopentadiene unit.",

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AU - Huffman, Mark A.

AU - Newman, David A.

AU - Tilset, Mats

AU - Tolman, William B.

AU - Vollhardt, K. Peter C.

PY - 1986/1/1

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N2 - Two synthetic strategies to the construction of heterobimetallic fulvalene (η5:η5-C10H8) complexes are reported. The first is based on the previously described monometallic ring-slippage products of (η5:η5-C10H8)Mo2-(CO)8and (η5:η5-C10H8)Ru2(CO)4that undergo recomplexation with a variety of metal carbonyls. The second utilizes a potentially iterative synthetic organic strategy in which cyclopentadienyl anion is subjected to an alkano-ylation–ring closure sequence that assembles a new attached cyclopentadiene unit.

AB - Two synthetic strategies to the construction of heterobimetallic fulvalene (η5:η5-C10H8) complexes are reported. The first is based on the previously described monometallic ring-slippage products of (η5:η5-C10H8)Mo2-(CO)8and (η5:η5-C10H8)Ru2(CO)4that undergo recomplexation with a variety of metal carbonyls. The second utilizes a potentially iterative synthetic organic strategy in which cyclopentadienyl anion is subjected to an alkano-ylation–ring closure sequence that assembles a new attached cyclopentadiene unit.

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Designed Syntheses of Heterobimetallic Fulvalene Complexes

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