Abstract
Porous polymeric materials can be prepared by using micromechanical deformations. The development of porous structures in the tension of polyolefin blends are studied with the goal of developing a novel technique to make porous films. It is found in polypropylene/polyethylene copolymer blends of near 50/50 weight ratio that a metallocene polymer pair can produce stable nanopores throughout a wide range of strain, ∼50-700%. Its strain-to-break was relatively high, although its continuous phase is a brittle polypropylene. The typical size of nanopores is 10-300 nm; they start to develop at approximately 50% strain. The disruption of craze-like structures into discrete nanopores seems to be the key mechanism in stabilizing pore development. Varying stretching direction and speed controls the pore morphology.
Original language | English (US) |
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Pages (from-to) | 3642-3650 |
Number of pages | 9 |
Journal | Journal of Applied Polymer Science |
Volume | 91 |
Issue number | 6 |
DOIs | |
State | Published - Mar 15 2004 |
Keywords
- Crazing
- Poly(propylene) (PP)
- Polyethylene copolymers
- Polyolefins
- Porous film