Development of flexible Mg and Ga co-doped ZnO thin films with wide band gap energy and transparent conductive characteristics

Seung Wook Shin, In Young Kim, G. V. Kishor, Yeong Yung Yoo, Young Baek Kim, Jae Yeong Heo, Gi Seok Heo, P. S. Patil, Jin Hyeok Kim, Jeong Yong Lee

Research output: Contribution to journalArticlepeer-review

25 Scopus citations

Abstract

The transparent conductive and flexible Mg and Ga co-doped ZnO (MGZO) thin films were prepared on poly-ethylene telepthalate (PET) by the RF magnetron sputtering technique at room temperature. The effects of different thicknesses on the structural, chemical, morphological, optical and electrical properties of MGZO thin films were investigated. X-ray diffraction studies showed that MGZO thin films were grown as a polycrystalline hexagonal wurtzite phase without a secondary phase. The peak intensities for the (0002) plane of MGZO thin films were enhanced with increasing thickness. A typical survey spectrum of MGZO thin films confirmed the presence of Mg, Ga, Zn and O resulting from MGZO films regardless of thickness. The MGZO thin films had a larger grain size with increasing thickness. The MGZO thin films showed the widest optical band gap energy of 3.91 eV (50 nm) and lowest electrical resistivity of 5.76 × 10-3 Ω cm (400 nm).

Original languageEnglish (US)
Pages (from-to)608-613
Number of pages6
JournalJournal of Alloys and Compounds
Volume585
DOIs
StatePublished - 2014

Bibliographical note

Funding Information:
This work is supported by the Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Korea government Ministry of Knowledge Economy (No.: 20124010203180 ) and development of 25% efficiency grade tandem CIGS thin film solar cell core technology of MKE (Ministry of Knowledge Economy) and ISKT (Korea Research council for Industrial Science and Technology) of Republic of Korea.

Keywords

  • Flexible thin film
  • Mg and Ga co-doped ZnO (MGZO)
  • RF magnetron sputtering
  • Transparent conducting oxide (TCO)

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