Abstract
In a previous study, it was demonstrated that all previous measurements of the electronically nonresonant fifth-order response for the intermolecular motions in liquid CS2 are dominated by third-order cascaded responses. In this study, phase matching was used to provide significant discrimination against the cascaded responses, thus directly measuring the fifth-order signal. Additional discrimination against the cascaded contributions was also provided by using the tensoral nature of the response.
Original language | English (US) |
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Pages (from-to) | 771-778 |
Number of pages | 8 |
Journal | Journal of Chemical Physics |
Volume | 113 |
Issue number | 2 |
DOIs | |
State | Published - Jul 2000 |