Dynamic 2D manganese(ii) isonicotinate framework with reversible crystal-to-amorphous transformation and selective guest adsorption

Dariusz Matoga; Barbara Gil; Wojciech Nitek; Alexander D. Todd; Christopher W. Bielawski

doi:10.1039/c4ce00647j

Dynamic 2D manganese(ii) isonicotinate framework with reversible crystal-to-amorphous transformation and selective guest adsorption

Dariusz Matoga, Barbara Gil, Wojciech Nitek, Alexander D. Todd, Christopher W. Bielawski

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

A 2D layered microporous isonicotinate-supported manganese(ii) metal-organic framework was found to exhibit a reversible crystal-to-amorphous transformation upon the removal and uptake of certain guest molecules. Unsaturated metal centers, generated in the dynamic framework upon activation, were found to facilitate the selective adsorption of CO₂versus N ₂.

Original language	English (US)
Pages (from-to)	4959-4962
Number of pages	4
Journal	CrystEngComm
Volume	16
Issue number	23
DOIs	https://doi.org/10.1039/c4ce00647j
State	Published - Jun 21 2014

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abstract = "A 2D layered microporous isonicotinate-supported manganese(ii) metal-organic framework was found to exhibit a reversible crystal-to-amorphous transformation upon the removal and uptake of certain guest molecules. Unsaturated metal centers, generated in the dynamic framework upon activation, were found to facilitate the selective adsorption of CO2versus N 2.",

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AU - Matoga, Dariusz

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AU - Todd, Alexander D.

AU - Bielawski, Christopher W.

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AB - A 2D layered microporous isonicotinate-supported manganese(ii) metal-organic framework was found to exhibit a reversible crystal-to-amorphous transformation upon the removal and uptake of certain guest molecules. Unsaturated metal centers, generated in the dynamic framework upon activation, were found to facilitate the selective adsorption of CO2versus N 2.

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Dynamic 2D manganese(ii) isonicotinate framework with reversible crystal-to-amorphous transformation and selective guest adsorption

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