Abstract
The influence of charge transfer from single Au atoms to TiO 2(110) on the photostimulated desorption (PSD) of 18O 2 has been studied using a measurement of the rate of hole transport which mediates PSD. Band bending effects observed experimentally and theoretically by density functional theory indicate that Auσ+ atoms are present. The presence of atomically dispersed Au on the TiO 2(110) surface with a constant coverage of preadsorbed 18O2 depresses the photoinduced hole transport rate from the bulk to the TiO2 surface and decreases the 18O 2 PSD yield. This indicates that single Au atoms donate a fraction of an electron to the surface, causing downward band bending. DFT calculations show that ∼0.2 electron transfers from single Au atoms to the O 2/TiO2(110) surface and the valence and conduction bands bend ∼0.6 eV downward. With increasing Au coverage, the positive charge per Au atom decreases due to the formation of small Au clusters.
Original language | English (US) |
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Pages (from-to) | 23848-23853 |
Number of pages | 6 |
Journal | Journal of Physical Chemistry C |
Volume | 115 |
Issue number | 48 |
DOIs | |
State | Published - Dec 8 2011 |