Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent: A convenient recyclable reagent for catalytic oxidation

Chenjie Zhu; Akira Yoshimura; Yunyang Wei; Victor N. Nemykin; Viktor Zhdankin

doi:10.1016/j.tetlet.2012.01.053

Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent: A convenient recyclable reagent for catalytic oxidation

Chenjie Zhu, Akira Yoshimura, Yunyang Wei, Victor N. Nemykin, Viktor Zhdankin

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Novel, efficient, and recyclable bifunctional catalysts bearing ionic liquid supported (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) and iodoarene moieties were developed and used for environmentally benign catalytic oxidation of alcohols. The reactions using peracetic acid as a green and practical co-oxidant afforded the corresponding carbonyl compounds in high yields under mild conditions and convenient work-up. Furthermore, these ionic liquid supported bifunctional catalysts could be simply recovered and reused.

Original language	English (US)
Pages (from-to)	1438-1444
Number of pages	7
Journal	Tetrahedron Letters
Volume	53
Issue number	12
DOIs	https://doi.org/10.1016/j.tetlet.2012.01.053
State	Published - Mar 21 2012

Bibliographical note

Funding Information:
Chenjie Zhu thanks the China Scholarship Council for supporting his visit to the University of Minnesota Duluth, and Project supported by the Research and Innovation Plan for Graduate Students of Jiangsu Higher Education Institutions (No. CX2211_0266). This work was supported by research grants from the National Science Foundation (CHE-1009038 and MRI CHE-0922366).

Copyright:
Copyright 2012 Elsevier B.V., All rights reserved.

Keywords

Hybrid catalysts
Hypervalent iodine
Ionic liquids
Oxidation
TEMPO

Access

10.1016/j.tetlet.2012.01.053

OpenUrl availability

Full text

Cite this

@article{8967deed5dfc4af7822a2e034665da23,

title = "Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent: A convenient recyclable reagent for catalytic oxidation",

abstract = "Novel, efficient, and recyclable bifunctional catalysts bearing ionic liquid supported (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) and iodoarene moieties were developed and used for environmentally benign catalytic oxidation of alcohols. The reactions using peracetic acid as a green and practical co-oxidant afforded the corresponding carbonyl compounds in high yields under mild conditions and convenient work-up. Furthermore, these ionic liquid supported bifunctional catalysts could be simply recovered and reused.",

keywords = "Hybrid catalysts, Hypervalent iodine, Ionic liquids, Oxidation, TEMPO",

author = "Chenjie Zhu and Akira Yoshimura and Yunyang Wei and Nemykin, {Victor N.} and Viktor Zhdankin",

note = "Funding Information: Chenjie Zhu thanks the China Scholarship Council for supporting his visit to the University of Minnesota Duluth, and Project supported by the Research and Innovation Plan for Graduate Students of Jiangsu Higher Education Institutions (No. CX2211_0266). This work was supported by research grants from the National Science Foundation (CHE-1009038 and MRI CHE-0922366). Copyright: Copyright 2012 Elsevier B.V., All rights reserved.",

year = "2012",

month = mar,

day = "21",

doi = "10.1016/j.tetlet.2012.01.053",

language = "English (US)",

volume = "53",

pages = "1438--1444",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "12",

}

TY - JOUR

T1 - Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent

T2 - A convenient recyclable reagent for catalytic oxidation

AU - Zhu, Chenjie

AU - Yoshimura, Akira

AU - Wei, Yunyang

AU - Nemykin, Victor N.

AU - Zhdankin, Viktor

N1 - Funding Information: Chenjie Zhu thanks the China Scholarship Council for supporting his visit to the University of Minnesota Duluth, and Project supported by the Research and Innovation Plan for Graduate Students of Jiangsu Higher Education Institutions (No. CX2211_0266). This work was supported by research grants from the National Science Foundation (CHE-1009038 and MRI CHE-0922366). Copyright: Copyright 2012 Elsevier B.V., All rights reserved.

PY - 2012/3/21

Y1 - 2012/3/21

N2 - Novel, efficient, and recyclable bifunctional catalysts bearing ionic liquid supported (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) and iodoarene moieties were developed and used for environmentally benign catalytic oxidation of alcohols. The reactions using peracetic acid as a green and practical co-oxidant afforded the corresponding carbonyl compounds in high yields under mild conditions and convenient work-up. Furthermore, these ionic liquid supported bifunctional catalysts could be simply recovered and reused.

AB - Novel, efficient, and recyclable bifunctional catalysts bearing ionic liquid supported (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) and iodoarene moieties were developed and used for environmentally benign catalytic oxidation of alcohols. The reactions using peracetic acid as a green and practical co-oxidant afforded the corresponding carbonyl compounds in high yields under mild conditions and convenient work-up. Furthermore, these ionic liquid supported bifunctional catalysts could be simply recovered and reused.

KW - Hybrid catalysts

KW - Hypervalent iodine

KW - Ionic liquids

KW - Oxidation

KW - TEMPO

UR - http://www.scopus.com/inward/record.url?scp=84857234561&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84857234561&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2012.01.053

DO - 10.1016/j.tetlet.2012.01.053

M3 - Article

AN - SCOPUS:84857234561

SN - 0040-4039

VL - 53

SP - 1438

EP - 1444

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 12

ER -

Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent: A convenient recyclable reagent for catalytic oxidation

Abstract

Bibliographical note

Keywords

Access

OpenUrl availability

Other files and links

Fingerprint

Cite this