Following the solvent directly during ultrafast excited state proton transfer

Sarah J. Schmidtke, David F. Underwood, David A. Blank

Research output: Contribution to journalArticlepeer-review

58 Scopus citations

Abstract

Excited state intramolecular proton transfer in 1-chloroacetylaminoanthraquinone is investigated from the perspective of the solvent. Using a new two-dimensional nonlinear optical spectroscopy the solvent response is probed directly as the proton transfer takes place. The measurements indicate that solvent reorganization controls the proton transfer in acetonitrile by dynamically shifting the position of equilibrium in the excited state, even on subpicosecond time scales.

Original languageEnglish (US)
Pages (from-to)8620-8621
Number of pages2
JournalJournal of the American Chemical Society
Volume126
Issue number28
DOIs
StatePublished - Jul 21 2004

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