Formation of an Alkylperoxoiron(III) Complex during Oxidations Catalyzed by μ‐Oxodiiron(III) Complexes

Stéphane Ménage, Elizabeth C. Wilkinson, Lawrence Que, Marc Fontecave

Research output: Contribution to journalArticlepeer-review

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Abstract

UV/Vis, resonance Raman, and EPR spectroscopy served in characterizing the alkylperoxoiron(III) complex 2, an intermediate in the oxidation of alcohols R'OH with alkyl hydroperoxides ROOH catalyzed by μ‐oxo complex 1. The results discussed may provide insight for studies of monooxygenases. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)203-205
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume34
Issue number2
DOIs
StatePublished - Feb 3 1995

Keywords

  • complexes with oxygen ligands
  • enzyme models
  • iron compounds
  • oxidations

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