Formation of an Alkylperoxoiron(III) Complex during Oxidations Catalyzed by μ‐Oxodiiron(III) Complexes

Stéphane Ménage; Elizabeth C. Wilkinson; Lawrence Que; Marc Fontecave

doi:10.1002/anie.199502031

Formation of an Alkylperoxoiron(III) Complex during Oxidations Catalyzed by μ‐Oxodiiron(III) Complexes

Stéphane Ménage, Elizabeth C. Wilkinson, Lawrence Que, Marc Fontecave

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

65 Scopus citations

Abstract

UV/Vis, resonance Raman, and EPR spectroscopy served in characterizing the alkylperoxoiron(III) complex 2, an intermediate in the oxidation of alcohols R'OH with alkyl hydroperoxides ROOH catalyzed by μ‐oxo complex 1. The results discussed may provide insight for studies of monooxygenases. (Figure Presented.)

Original language	English (US)
Pages (from-to)	203-205
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	34
Issue number	2
DOIs	https://doi.org/10.1002/anie.199502031
State	Published - Feb 3 1995

Keywords

complexes with oxygen ligands
enzyme models
iron compounds
oxidations

Access

10.1002/anie.199502031

OpenUrl availability

Full text

Cite this

@article{9e5c47a0522b4af2b2ec56287f331092,

title = "Formation of an Alkylperoxoiron(III) Complex during Oxidations Catalyzed by μ‐Oxodiiron(III) Complexes",

abstract = "UV/Vis, resonance Raman, and EPR spectroscopy served in characterizing the alkylperoxoiron(III) complex 2, an intermediate in the oxidation of alcohols R'OH with alkyl hydroperoxides ROOH catalyzed by μ‐oxo complex 1. The results discussed may provide insight for studies of monooxygenases. (Figure Presented.)",

keywords = "complexes with oxygen ligands, enzyme models, iron compounds, oxidations",

author = "St{\'e}phane M{\'e}nage and Wilkinson, {Elizabeth C.} and Lawrence Que and Marc Fontecave",

year = "1995",

month = feb,

day = "3",

doi = "10.1002/anie.199502031",

language = "English (US)",

volume = "34",

pages = "203--205",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "John Wiley and Sons Ltd",

number = "2",

}

TY - JOUR

T1 - Formation of an Alkylperoxoiron(III) Complex during Oxidations Catalyzed by μ‐Oxodiiron(III) Complexes

AU - Ménage, Stéphane

AU - Wilkinson, Elizabeth C.

AU - Que, Lawrence

AU - Fontecave, Marc

PY - 1995/2/3

Y1 - 1995/2/3

N2 - UV/Vis, resonance Raman, and EPR spectroscopy served in characterizing the alkylperoxoiron(III) complex 2, an intermediate in the oxidation of alcohols R'OH with alkyl hydroperoxides ROOH catalyzed by μ‐oxo complex 1. The results discussed may provide insight for studies of monooxygenases. (Figure Presented.)

AB - UV/Vis, resonance Raman, and EPR spectroscopy served in characterizing the alkylperoxoiron(III) complex 2, an intermediate in the oxidation of alcohols R'OH with alkyl hydroperoxides ROOH catalyzed by μ‐oxo complex 1. The results discussed may provide insight for studies of monooxygenases. (Figure Presented.)

KW - complexes with oxygen ligands

KW - enzyme models

KW - iron compounds

KW - oxidations

UR - http://www.scopus.com/inward/record.url?scp=33748240118&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33748240118&partnerID=8YFLogxK

U2 - 10.1002/anie.199502031

DO - 10.1002/anie.199502031

M3 - Article

AN - SCOPUS:33748240118

SN - 0570-0833

VL - 34

SP - 203

EP - 205

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 2

ER -

Formation of an Alkylperoxoiron(III) Complex during Oxidations Catalyzed by μ‐Oxodiiron(III) Complexes

Abstract

Keywords

Access

OpenUrl availability

Other files and links

Fingerprint

Cite this