Abstract
(Chemical Equation Presented) A ferryl cation in water: Iron(II) coordinated by the pentadentate ligand L reacts with H2O2 to form a low-spin FeIV=O complex with S = 1 (2 in scheme) under conditions similar to those of the classical Fenton reaction. Complex 2 differs from a recently obtained high-spin aquated oxoiron(IV) species and demonstrates the role of the supporting polydentate ligand in controlling spin state and product formation.
Original language | English (US) |
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Pages (from-to) | 5681-5684 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 45 |
Issue number | 34 |
DOIs | |
State | Published - Sep 2 2006 |
Keywords
- Coordination modes
- Iron
- N ligands
- Oxidation
- Oxo ligands