From 1D to 3D single-crystal-to-single-crystal structural transformations based on linear polyanion [Mn 4(H 2O) 18WZnMn 2(H 2O) 2(ZnW 9O 34) 2] 4-

Lian Xu Shi, Wen Feng Zhao, Xuan Xu, JING TANG, Chuan De Wu

Research output: Contribution to journalArticlepeer-review

26 Scopus citations

Abstract

A 1D anionic polyoxometalate, [Mn 4(H 2O) 18WZnMn 2(H 2O) 2(ZnW 9O 34) 2] 4-, undergoes 1D to 3D single-crystal-to-single-crystal structural transformations that are induced by transition-metal cations (Co 2+ and Cu 2+) and solvent molecules. These solid materials present interesting catalytic activity for the oxidative aromatization of Hantzsch 1, 4-dihydropyridines that is dependent on the inserted heterogeneous metal cations.

Original languageEnglish (US)
Pages (from-to)12387-12389
Number of pages3
JournalInorganic Chemistry
Volume50
Issue number24
DOIs
StatePublished - Dec 19 2011

Fingerprint Dive into the research topics of 'From 1D to 3D single-crystal-to-single-crystal structural transformations based on linear polyanion [Mn <sub>4</sub>(H <sub>2</sub>O) <sub>18</sub>WZnMn <sub>2</sub>(H <sub>2</sub>O) <sub>2</sub>(ZnW <sub>9</sub>O <sub>34</sub>) <sub>2</sub>] <sup>4-</sup>'. Together they form a unique fingerprint.

Cite this