TY - JOUR
T1 - Fused pyridazines
T2 - Rigid multidentates for designing and fine-tuning the structure of hybrid organic/inorganic frameworks
AU - Solntsev, Pavlo V.
AU - Sieler, Joachim
AU - Krautscheid, Harald
AU - Domasevitch, Konstantin V.
PY - 2004/4/21
Y1 - 2004/4/21
N2 - Fused pyridazines (1,2,3,6,7,8-hexahydro-cinnolino[5,4,3-cde]cinnoline, L and its 2,2,7,7-tetramethyl derivative, Me4L) are designed as rigid multidentate ligands for the construction of framework solids. In combination with copper(I) bromide (iodide) they provide excellent structural examples for predictive engineering and the possibilities for further fine-tuning of the framework architectures facilitated by the tetradentate function of the ligands and effective cooperation of organic and inorganic bridges. This study features control over helical structures for (CuX)n chains and homo/heterochiral combination of the helices in the lattice, the design of a range of channelled and tubular CuX networks and the structural significance of ligand shape complementarity. 3D tetragonal Cu2X2(L) frameworks exist either as chiral or achiral supramolecular isomers Cu 2I2(Me4L) and Cu12l 12Cu(CH3CN)}3(L)6-Cu 3l6-CH3CN illustrate 3D hexagonal channelled and tubular arrays; Cu2I2(Me4L)(CH 3CN) and Cu4I4(L)(CH3CN)2 complexes are 1 D polymers.
AB - Fused pyridazines (1,2,3,6,7,8-hexahydro-cinnolino[5,4,3-cde]cinnoline, L and its 2,2,7,7-tetramethyl derivative, Me4L) are designed as rigid multidentate ligands for the construction of framework solids. In combination with copper(I) bromide (iodide) they provide excellent structural examples for predictive engineering and the possibilities for further fine-tuning of the framework architectures facilitated by the tetradentate function of the ligands and effective cooperation of organic and inorganic bridges. This study features control over helical structures for (CuX)n chains and homo/heterochiral combination of the helices in the lattice, the design of a range of channelled and tubular CuX networks and the structural significance of ligand shape complementarity. 3D tetragonal Cu2X2(L) frameworks exist either as chiral or achiral supramolecular isomers Cu 2I2(Me4L) and Cu12l 12Cu(CH3CN)}3(L)6-Cu 3l6-CH3CN illustrate 3D hexagonal channelled and tubular arrays; Cu2I2(Me4L)(CH 3CN) and Cu4I4(L)(CH3CN)2 complexes are 1 D polymers.
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U2 - 10.1039/B316561B
DO - 10.1039/B316561B
M3 - Article
AN - SCOPUS:2342617526
SN - 1477-9226
SP - 1153
EP - 1158
JO - Dalton Transactions
JF - Dalton Transactions
IS - 8
ER -