Highly reduced organometallics 52. Synthesis and chemistry of tricarbonylnitrosylmanganate(2-), [Mn(CO)3(NO)]2-

Yu Sen Chen; John E. Ellis

doi:10.1016/S0020-1693(99)00546-0

Highly reduced organometallics 52. Synthesis and chemistry of tricarbonylnitrosylmanganate(2-), [Mn(CO)₃(NO)]^2-

Yu Sen Chen, John E. Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Treatment of Mn(CO)₃(NO)(PPh₃) in THF at 20°C with excess sodium amalgam, followed by treatment with cryptand 2.2.2, or with two equiv. of potassium tri-sec-butylborohydride afforded high isolated yields (≥ 80%) of air sensitive yellow solids identified as [Na(crypt.2.2.2)]₂[Mn(CO)₃(NO)] and K₂[Mn(CO)₃(NO)], respectively. These products contain the only known mixed carbonylnitrosylmetallate dianion, isoelectronic with [Fe(CO)₄]^2- and [Mn(CO)₄]^3-. Reactions of [Mn(CO)₃(NO)]^2- with Ph₃SnCl, Mn(CO)₄(NO) and Fe(CO)₅, followed by metathesis, provided the new derivatives [Et₄N][Mn(CO)₃(NO)(SnPh₃)], [PPN]₂[Mn₂(CO)₆(NO)₂], and [PPN]₂[MnFe(CO)₇(NO)]. On the basis of IR spectral data the latter two have been formulated to contain non-bridged structures analogous to that previously established for the isoelectronic salt [PPN]₂[Fe₂(CO)₈]. (C) 2000 Elsevier Science S.A.

Original language	English (US)
Pages (from-to)	675-682
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	300-302
DOIs	https://doi.org/10.1016/S0020-1693(99)00546-0
State	Published - Apr 30 2000

Bibliographical note

Funding Information:
We sincerely thank the US National Science Foundation and the donors of the Petroleum Research Fund, administered by the American Chemical Society for financial support and Christine Lundby for her expert assistance with the manuscript. We also are indebted to Robert E. Stevens and Professor Wayne L. Gladfelter for advice on how to best prepare [Mn(CO) 4 (NO)] from readily available precursors.

Keywords

Carbonyl complexes
Manganese complexes
Nitrosyl complexes
Organophosphane complexes
Organotin

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title = "Highly reduced organometallics 52. Synthesis and chemistry of tricarbonylnitrosylmanganate(2-), [Mn(CO)3(NO)]2-",

abstract = "Treatment of Mn(CO)3(NO)(PPh3) in THF at 20°C with excess sodium amalgam, followed by treatment with cryptand 2.2.2, or with two equiv. of potassium tri-sec-butylborohydride afforded high isolated yields (≥ 80%) of air sensitive yellow solids identified as [Na(crypt.2.2.2)]2[Mn(CO)3(NO)] and K2[Mn(CO)3(NO)], respectively. These products contain the only known mixed carbonylnitrosylmetallate dianion, isoelectronic with [Fe(CO)4]2- and [Mn(CO)4]3-. Reactions of [Mn(CO)3(NO)]2- with Ph3SnCl, Mn(CO)4(NO) and Fe(CO)5, followed by metathesis, provided the new derivatives [Et4N][Mn(CO)3(NO)(SnPh3)], [PPN]2[Mn2(CO)6(NO)2], and [PPN]2[MnFe(CO)7(NO)]. On the basis of IR spectral data the latter two have been formulated to contain non-bridged structures analogous to that previously established for the isoelectronic salt [PPN]2[Fe2(CO)8]. (C) 2000 Elsevier Science S.A.",

keywords = "Carbonyl complexes, Manganese complexes, Nitrosyl complexes, Organophosphane complexes, Organotin",

author = "Chen, {Yu Sen} and Ellis, {John E.}",

note = "Funding Information: We sincerely thank the US National Science Foundation and the donors of the Petroleum Research Fund, administered by the American Chemical Society for financial support and Christine Lundby for her expert assistance with the manuscript. We also are indebted to Robert E. Stevens and Professor Wayne L. Gladfelter for advice on how to best prepare [Mn(CO) 4 (NO)] from readily available precursors. ",

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AU - Chen, Yu Sen

AU - Ellis, John E.

N1 - Funding Information: We sincerely thank the US National Science Foundation and the donors of the Petroleum Research Fund, administered by the American Chemical Society for financial support and Christine Lundby for her expert assistance with the manuscript. We also are indebted to Robert E. Stevens and Professor Wayne L. Gladfelter for advice on how to best prepare [Mn(CO) 4 (NO)] from readily available precursors.

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N2 - Treatment of Mn(CO)3(NO)(PPh3) in THF at 20°C with excess sodium amalgam, followed by treatment with cryptand 2.2.2, or with two equiv. of potassium tri-sec-butylborohydride afforded high isolated yields (≥ 80%) of air sensitive yellow solids identified as [Na(crypt.2.2.2)]2[Mn(CO)3(NO)] and K2[Mn(CO)3(NO)], respectively. These products contain the only known mixed carbonylnitrosylmetallate dianion, isoelectronic with [Fe(CO)4]2- and [Mn(CO)4]3-. Reactions of [Mn(CO)3(NO)]2- with Ph3SnCl, Mn(CO)4(NO) and Fe(CO)5, followed by metathesis, provided the new derivatives [Et4N][Mn(CO)3(NO)(SnPh3)], [PPN]2[Mn2(CO)6(NO)2], and [PPN]2[MnFe(CO)7(NO)]. On the basis of IR spectral data the latter two have been formulated to contain non-bridged structures analogous to that previously established for the isoelectronic salt [PPN]2[Fe2(CO)8]. (C) 2000 Elsevier Science S.A.

AB - Treatment of Mn(CO)3(NO)(PPh3) in THF at 20°C with excess sodium amalgam, followed by treatment with cryptand 2.2.2, or with two equiv. of potassium tri-sec-butylborohydride afforded high isolated yields (≥ 80%) of air sensitive yellow solids identified as [Na(crypt.2.2.2)]2[Mn(CO)3(NO)] and K2[Mn(CO)3(NO)], respectively. These products contain the only known mixed carbonylnitrosylmetallate dianion, isoelectronic with [Fe(CO)4]2- and [Mn(CO)4]3-. Reactions of [Mn(CO)3(NO)]2- with Ph3SnCl, Mn(CO)4(NO) and Fe(CO)5, followed by metathesis, provided the new derivatives [Et4N][Mn(CO)3(NO)(SnPh3)], [PPN]2[Mn2(CO)6(NO)2], and [PPN]2[MnFe(CO)7(NO)]. On the basis of IR spectral data the latter two have been formulated to contain non-bridged structures analogous to that previously established for the isoelectronic salt [PPN]2[Fe2(CO)8]. (C) 2000 Elsevier Science S.A.

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