Hydride phase formation in carbon supported palladium hydride nanoparticles by in situ EXAFS and XRD

A. L. Bugaev; A. A. Guda; K. A. Lomachenko; A. Lazzarini; V. V. Srabionyan; J. G. Vitillo; A. Piovano; E. Groppo; L. A. Bugaev; A. V. Soldatov; V. P. Dmitriev; R. Pellegrini; J. A. Van Bokhoven; C. Lamberti

doi:10.1088/1742-6596/712/1/012032

Hydride phase formation in carbon supported palladium hydride nanoparticles by in situ EXAFS and XRD

A. L. Bugaev, A. A. Guda, K. A. Lomachenko, A. Lazzarini, V. V. Srabionyan, J. G. Vitillo, A. Piovano, E. Groppo, L. A. Bugaev, A. V. Soldatov, V. P. Dmitriev, R. Pellegrini, J. A. Van Bokhoven, C. Lamberti

Chemistry (Twin Cities)

Research output: Contribution to journal › Conference article › peer-review

34 Scopus citations

Abstract

In the current work we present a detailed analysis of the hydride phase formation in industrial Pd/C nanocatalysts by means of combined in situ X-ray absorption spectroscopy (EXAFS), X-ray diffraction (XRD) and volumetric measurements for the temperatures from - 10 to 50 °C in the hydrogen pressure range from 0 to 1000 mbar. α- and β- hydride phases are clearly distinguished in XRD. For the first time, H/Pd atomic ratio were obtained by theoretical fitting of the near-edge region of the absorption spectra (XANES) and compared with volumetric measurements.

Original language	English (US)
Article number	012032
Journal	Journal of Physics: Conference Series
Volume	712
Issue number	1
DOIs	https://doi.org/10.1088/1742-6596/712/1/012032
State	Published - 2016
Event	16th International Conference on X-Ray Absorption Fine Structure, XAFS 2015 - Karlsruhe, Germany Duration: Aug 23 2015 → Aug 28 2015

Bibliographical note

Funding Information:
The research was supported by the Mega-Grant of the Ministry of Education and Science of the Russian Federation (14.Y26.31.0001). ALB, AAG acknowledge the Grant of President of Russian Federation for Young Scientists support MK3206.2014.2.

Access

10.1088/1742-6596/712/1/012032

OpenUrl availability

Full text

Cite this

Bugaev, A. L., Guda, A. A., Lomachenko, K. A., Lazzarini, A., Srabionyan, V. V., Vitillo, J. G., Piovano, A., Groppo, E., Bugaev, L. A., Soldatov, A. V., Dmitriev, V. P., Pellegrini, R., Van Bokhoven, J. A., & Lamberti, C. (2016). Hydride phase formation in carbon supported palladium hydride nanoparticles by in situ EXAFS and XRD. Journal of Physics: Conference Series, 712(1), Article 012032. https://doi.org/10.1088/1742-6596/712/1/012032

Bugaev, AL, Guda, AA, Lomachenko, KA, Lazzarini, A, Srabionyan, VV, Vitillo, JG, Piovano, A, Groppo, E, Bugaev, LA, Soldatov, AV, Dmitriev, VP, Pellegrini, R, Van Bokhoven, JA & Lamberti, C 2016, 'Hydride phase formation in carbon supported palladium hydride nanoparticles by in situ EXAFS and XRD', Journal of Physics: Conference Series, vol. 712, no. 1, 012032. https://doi.org/10.1088/1742-6596/712/1/012032

@article{642dad766ec84a9bb0deb22155a7743e,

title = "Hydride phase formation in carbon supported palladium hydride nanoparticles by in situ EXAFS and XRD",

abstract = "In the current work we present a detailed analysis of the hydride phase formation in industrial Pd/C nanocatalysts by means of combined in situ X-ray absorption spectroscopy (EXAFS), X-ray diffraction (XRD) and volumetric measurements for the temperatures from - 10 to 50 °C in the hydrogen pressure range from 0 to 1000 mbar. α- and β- hydride phases are clearly distinguished in XRD. For the first time, H/Pd atomic ratio were obtained by theoretical fitting of the near-edge region of the absorption spectra (XANES) and compared with volumetric measurements.",

author = "Bugaev, {A. L.} and Guda, {A. A.} and Lomachenko, {K. A.} and A. Lazzarini and Srabionyan, {V. V.} and Vitillo, {J. G.} and A. Piovano and E. Groppo and Bugaev, {L. A.} and Soldatov, {A. V.} and Dmitriev, {V. P.} and R. Pellegrini and {Van Bokhoven}, {J. A.} and C. Lamberti",

note = "Funding Information: The research was supported by the Mega-Grant of the Ministry of Education and Science of the Russian Federation (14.Y26.31.0001). ALB, AAG acknowledge the Grant of President of Russian Federation for Young Scientists support MK3206.2014.2.; 16th International Conference on X-Ray Absorption Fine Structure, XAFS 2015 ; Conference date: 23-08-2015 Through 28-08-2015",

year = "2016",

doi = "10.1088/1742-6596/712/1/012032",

language = "English (US)",

volume = "712",

journal = "Journal of Physics: Conference Series",

issn = "1742-6588",

publisher = "IOP Publishing Ltd.",

number = "1",

}

TY - JOUR

T1 - Hydride phase formation in carbon supported palladium hydride nanoparticles by in situ EXAFS and XRD

AU - Bugaev, A. L.

AU - Guda, A. A.

AU - Lomachenko, K. A.

AU - Lazzarini, A.

AU - Srabionyan, V. V.

AU - Vitillo, J. G.

AU - Piovano, A.

AU - Groppo, E.

AU - Bugaev, L. A.

AU - Soldatov, A. V.

AU - Dmitriev, V. P.

AU - Pellegrini, R.

AU - Van Bokhoven, J. A.

AU - Lamberti, C.

N1 - Funding Information: The research was supported by the Mega-Grant of the Ministry of Education and Science of the Russian Federation (14.Y26.31.0001). ALB, AAG acknowledge the Grant of President of Russian Federation for Young Scientists support MK3206.2014.2.

PY - 2016

Y1 - 2016

N2 - In the current work we present a detailed analysis of the hydride phase formation in industrial Pd/C nanocatalysts by means of combined in situ X-ray absorption spectroscopy (EXAFS), X-ray diffraction (XRD) and volumetric measurements for the temperatures from - 10 to 50 °C in the hydrogen pressure range from 0 to 1000 mbar. α- and β- hydride phases are clearly distinguished in XRD. For the first time, H/Pd atomic ratio were obtained by theoretical fitting of the near-edge region of the absorption spectra (XANES) and compared with volumetric measurements.

AB - In the current work we present a detailed analysis of the hydride phase formation in industrial Pd/C nanocatalysts by means of combined in situ X-ray absorption spectroscopy (EXAFS), X-ray diffraction (XRD) and volumetric measurements for the temperatures from - 10 to 50 °C in the hydrogen pressure range from 0 to 1000 mbar. α- and β- hydride phases are clearly distinguished in XRD. For the first time, H/Pd atomic ratio were obtained by theoretical fitting of the near-edge region of the absorption spectra (XANES) and compared with volumetric measurements.

UR - http://www.scopus.com/inward/record.url?scp=84978741644&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84978741644&partnerID=8YFLogxK

U2 - 10.1088/1742-6596/712/1/012032

DO - 10.1088/1742-6596/712/1/012032

M3 - Conference article

AN - SCOPUS:84978741644

SN - 1742-6588

VL - 712

JO - Journal of Physics: Conference Series

JF - Journal of Physics: Conference Series

IS - 1

M1 - 012032

T2 - 16th International Conference on X-Ray Absorption Fine Structure, XAFS 2015

Y2 - 23 August 2015 through 28 August 2015

ER -

Hydride phase formation in carbon supported palladium hydride nanoparticles by in situ EXAFS and XRD

Abstract

Bibliographical note

Access

OpenUrl availability

Other files and links

Fingerprint

Cite this