Abstract
An isostructural series of Np(V) MOFs with shp-topology were synthesized and characterized. X-ray diffraction data revealed an unusual wheel-shaped node of 18 neptunyl polyhedra stabilized in the framework. Strong distortion in local coordination of the neptunium atoms is evidenced by Np-Oyl bond lengths that lie outside the typical range for Np(V). The structure was further interrogated by Raman spectroscopy and density functional theory calculations to assign the vibrational modes.
Original language | English (US) |
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Pages (from-to) | 11842-11846 |
Number of pages | 5 |
Journal | Journal of the American Chemical Society |
Volume | 141 |
Issue number | 30 |
DOIs | |
State | Published - Jul 31 2019 |
Bibliographical note
Publisher Copyright:© 2019 American Chemical Society.