Influence of aluminum doping on ferrihydrite nanoparticle reactivity

Teresa L. Jentzsch, R. Lee Penn

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

The composition of natural ferrihydrite varies considerably, especially in terms of aluminum and silicon substitution. This work examines the influence of aluminum content on the redox reactivity of ferrihydrite nanoparticles as determined by kinetic studies of the reductive dissolution of the particles by hydroquinone. Transition state theory applied to variable-temperature experiments is used to measure the activation enthalpy and entropy. The presence of small amounts of aluminum (0-2.1 mol % substitution) causes a decrease in ΔH and an increase in ΔS, resulting in an overall increase in reactivity.

Original languageEnglish (US)
Pages (from-to)11746-11750
Number of pages5
JournalJournal of Physical Chemistry B
Volume110
Issue number24
DOIs
StatePublished - Jun 22 2006

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