Infrared and manometric evidence for the formation of the [Ag(CO) 3]+ complex ion at high PCO

Jeffrey J. Rack, Bahram Moasser, Jerry D. Gargulak, Wayne L Gladfelter, Hans D. Hochheimer, Steven H. Strauss

Research output: Contribution to journalArticlepeer-review

35 Scopus citations

Abstract

At high pressures of CO, the Ag+ salt of the weekly coordinating anion [Nb(OTeF5)6]- takes up three equiv. CO reversibly both in the solid state and in 1,1,2-C2Cl 3F3 solution; the CO ligands can be removed from [Ag(CO)3][Nb(OTeF5)6] under vacuum at 25 °C but none are removed at -78 °C; IR ν(CO) values are 2192 cm-1 for [Ag(CO)3]+, 2198 cm-1 for [Ag(CO) 2]+, and 2208 cm-1 for [AgCO]+.

Original languageEnglish (US)
Pages (from-to)685-686
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number6
DOIs
StatePublished - Dec 1 1994

Fingerprint Dive into the research topics of 'Infrared and manometric evidence for the formation of the [Ag(CO) <sub>3</sub>]<sup>+</sup> complex ion at high P<sub>CO</sub>'. Together they form a unique fingerprint.

Cite this