TY - JOUR
T1 - Infrared and manometric evidence for the formation of the [Ag(CO) 3]+ complex ion at high PCO
AU - Rack, Jeffrey J.
AU - Moasser, Bahram
AU - Gargulak, Jerry D.
AU - Gladfelter, Wayne L.
AU - Hochheimer, Hans D.
AU - Strauss, Steven H.
PY - 1994
Y1 - 1994
N2 - At high pressures of CO, the Ag+ salt of the weekly coordinating anion [Nb(OTeF5)6]- takes up three equiv. CO reversibly both in the solid state and in 1,1,2-C2Cl 3F3 solution; the CO ligands can be removed from [Ag(CO)3][Nb(OTeF5)6] under vacuum at 25 °C but none are removed at -78 °C; IR ν(CO) values are 2192 cm-1 for [Ag(CO)3]+, 2198 cm-1 for [Ag(CO) 2]+, and 2208 cm-1 for [AgCO]+.
AB - At high pressures of CO, the Ag+ salt of the weekly coordinating anion [Nb(OTeF5)6]- takes up three equiv. CO reversibly both in the solid state and in 1,1,2-C2Cl 3F3 solution; the CO ligands can be removed from [Ag(CO)3][Nb(OTeF5)6] under vacuum at 25 °C but none are removed at -78 °C; IR ν(CO) values are 2192 cm-1 for [Ag(CO)3]+, 2198 cm-1 for [Ag(CO) 2]+, and 2208 cm-1 for [AgCO]+.
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U2 - 10.1039/C39940000685
DO - 10.1039/C39940000685
M3 - Article
AN - SCOPUS:37049084584
SN - 0022-4936
SP - 685
EP - 686
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 6
ER -