Interdiffusion Stomatal Movement in Efficient Multiple-Cation-Based Perovskite Solar Cells

Cong Li; Zhinan Zhu; Bingqiang Niu; Fu Yang; Xinpeng Chen; Yingke Ren; Peng Zhong; Shuzi Hayase; Tianhong Cui; Rusen Yang

doi:10.1021/acsami.0c10873

Interdiffusion Stomatal Movement in Efficient Multiple-Cation-Based Perovskite Solar Cells

Cong Li, Zhinan Zhu, Bingqiang Niu, Fu Yang, Xinpeng Chen, Yingke Ren, Peng Zhong, Shuzi Hayase, Tianhong Cui, Rusen Yang

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The composition and crystallization process are essential for high-quality perovskite films. Cesium (Cs) and methylammonium chlorine (MACl) were found to affect the crystallization kinetics of perovskite, and the performance and stability of corresponding devices were greatly improved. We adopted an ion exchange method to remove MACl vapor and add Cs to form a multiple-cation-based perovskite film. With the increase of annealing time, Cl- from cesium chloride (CsCl) and MA from methylammonium bromide (MABr) formed gradually MACl vapor, and the porosity of surface morphology improved accordingly. The highly crystallized and compact CsyMAx - yFA1 - xPbI3 - xBrx perovskite film with different compositions was eventually obtained. The effects of the amount of MABr on the property of perovskite films and on the performance of the corresponding perovskite solar cells (PerSCs) were systematically studied. The PerSCs derived from 12 mg of MABr exhibit the best photovoltaic performance with a power conversion efficiency of 21.57% under 1 sun illumination.

Original language	English (US)
Pages (from-to)	35105-35112
Number of pages	8
Journal	ACS Applied Materials and Interfaces
Volume	12
Issue number	31
DOIs	https://doi.org/10.1021/acsami.0c10873
State	Published - Aug 5 2020
Externally published	Yes

Bibliographical note

Funding Information:
We thank Xidian University for its support. This work was financially supported by the National R&D Program of China under grant no.2017YFA0207400, the National Natural Science Foundation of China under grant no. 11604250, the National Natural Science Foundation of Shaanxi Province under grant nos. 2019JCW-17, 2019JQ-654, 2019JQ-155, and 2019JQ-003, and the Fundamental Research Funds for the Central Universities, China under grant no. JB191406.

Funding Information:
We thank Xidian University for its support. This work was financially supported by the National R&D Program of China under grant no.2017YFA0207400, the National Natural Science Foundation of China under grant no. 11604250, the National Natural Science Foundation of Shaanxi Province under grant nos. 2019JCW-17 2019JQ-654, 2019JQ-155, and 2019JQ-003, and the Fundamental Research Funds for the Central Universities, China under grant no. JB191406.

Publisher Copyright:
Copyright © 2020 American Chemical Society.

Keywords

crystallinity
multiple-cation
perovskite solar cells
planar structure
stomatal movement

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title = "Interdiffusion Stomatal Movement in Efficient Multiple-Cation-Based Perovskite Solar Cells",

abstract = "The composition and crystallization process are essential for high-quality perovskite films. Cesium (Cs) and methylammonium chlorine (MACl) were found to affect the crystallization kinetics of perovskite, and the performance and stability of corresponding devices were greatly improved. We adopted an ion exchange method to remove MACl vapor and add Cs to form a multiple-cation-based perovskite film. With the increase of annealing time, Cl- from cesium chloride (CsCl) and MA from methylammonium bromide (MABr) formed gradually MACl vapor, and the porosity of surface morphology improved accordingly. The highly crystallized and compact CsyMAx - yFA1 - xPbI3 - xBrx perovskite film with different compositions was eventually obtained. The effects of the amount of MABr on the property of perovskite films and on the performance of the corresponding perovskite solar cells (PerSCs) were systematically studied. The PerSCs derived from 12 mg of MABr exhibit the best photovoltaic performance with a power conversion efficiency of 21.57% under 1 sun illumination.",

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note = "Funding Information: We thank Xidian University for its support. This work was financially supported by the National R&D Program of China under grant no.2017YFA0207400, the National Natural Science Foundation of China under grant no. 11604250, the National Natural Science Foundation of Shaanxi Province under grant nos. 2019JCW-17, 2019JQ-654, 2019JQ-155, and 2019JQ-003, and the Fundamental Research Funds for the Central Universities, China under grant no. JB191406. Funding Information: We thank Xidian University for its support. This work was financially supported by the National R&D Program of China under grant no.2017YFA0207400, the National Natural Science Foundation of China under grant no. 11604250, the National Natural Science Foundation of Shaanxi Province under grant nos. 2019JCW-17 2019JQ-654, 2019JQ-155, and 2019JQ-003, and the Fundamental Research Funds for the Central Universities, China under grant no. JB191406. Publisher Copyright: Copyright {\textcopyright} 2020 American Chemical Society.",

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AU - Chen, Xinpeng

AU - Ren, Yingke

AU - Zhong, Peng

AU - Hayase, Shuzi

AU - Cui, Tianhong

AU - Yang, Rusen

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N2 - The composition and crystallization process are essential for high-quality perovskite films. Cesium (Cs) and methylammonium chlorine (MACl) were found to affect the crystallization kinetics of perovskite, and the performance and stability of corresponding devices were greatly improved. We adopted an ion exchange method to remove MACl vapor and add Cs to form a multiple-cation-based perovskite film. With the increase of annealing time, Cl- from cesium chloride (CsCl) and MA from methylammonium bromide (MABr) formed gradually MACl vapor, and the porosity of surface morphology improved accordingly. The highly crystallized and compact CsyMAx - yFA1 - xPbI3 - xBrx perovskite film with different compositions was eventually obtained. The effects of the amount of MABr on the property of perovskite films and on the performance of the corresponding perovskite solar cells (PerSCs) were systematically studied. The PerSCs derived from 12 mg of MABr exhibit the best photovoltaic performance with a power conversion efficiency of 21.57% under 1 sun illumination.

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KW - perovskite solar cells

KW - planar structure

KW - stomatal movement

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Interdiffusion Stomatal Movement in Efficient Multiple-Cation-Based Perovskite Solar Cells

Abstract

Bibliographical note

Keywords

UN SDGs

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