Inverse vulcanization of elemental sulfur with 1,4-diphenylbutadiyne for cathode materials in Li-S batteries

Philip T. Dirlam; Adam G. Simmonds; Tristan S. Kleine; Ngoc A. Nguyen; Laura E. Anderson; Adam O. Klever; Alexander Florian; Philip J. Costanzo; Patrick Theato; Michael E. Mackay; Richard S. Glass; Kookheon Char; Jeffrey Pyun

doi:10.1039/c5ra01188d

Inverse vulcanization of elemental sulfur with 1,4-diphenylbutadiyne for cathode materials in Li-S batteries

Philip T. Dirlam, Adam G. Simmonds, Tristan S. Kleine, Ngoc A. Nguyen, Laura E. Anderson, Adam O. Klever, Alexander Florian, Philip J. Costanzo, Patrick Theato, Michael E. Mackay, Richard S. Glass, Kookheon Char, Jeffrey Pyun

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

145 Scopus citations

Abstract

High sulfur content copolymers were prepared via inverse vulcanization of sulfur with 1,4-diphenylbutadiyne (DiPhDY) for use as the active cathode material in lithium-sulfur batteries. These sulfur-rich polymers exhibited excellent capacity retention (800 mA h g^-1 at 300 cycles) and extended battery lifetimes of over 850 cycles at C/5 rate.

Original language	English (US)
Pages (from-to)	24718-24722
Number of pages	5
Journal	RSC Advances
Volume	5
Issue number	31
DOIs	https://doi.org/10.1039/c5ra01188d
State	Published - 2015

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Publisher Copyright:
© The Royal Society of Chemistry 2015.

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Dirlam, P. T., Simmonds, A. G., Kleine, T. S., Nguyen, N. A., Anderson, L. E., Klever, A. O., Florian, A., Costanzo, P. J., Theato, P., Mackay, M. E., Glass, R. S., Char, K., & Pyun, J. (2015). Inverse vulcanization of elemental sulfur with 1,4-diphenylbutadiyne for cathode materials in Li-S batteries. RSC Advances, 5(31), 24718-24722. https://doi.org/10.1039/c5ra01188d

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abstract = "High sulfur content copolymers were prepared via inverse vulcanization of sulfur with 1,4-diphenylbutadiyne (DiPhDY) for use as the active cathode material in lithium-sulfur batteries. These sulfur-rich polymers exhibited excellent capacity retention (800 mA h g-1 at 300 cycles) and extended battery lifetimes of over 850 cycles at C/5 rate.",

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AU - Kleine, Tristan S.

AU - Nguyen, Ngoc A.

AU - Anderson, Laura E.

AU - Klever, Adam O.

AU - Florian, Alexander

AU - Costanzo, Philip J.

AU - Theato, Patrick

AU - Mackay, Michael E.

AU - Glass, Richard S.

AU - Char, Kookheon

AU - Pyun, Jeffrey

PY - 2015

Y1 - 2015

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AB - High sulfur content copolymers were prepared via inverse vulcanization of sulfur with 1,4-diphenylbutadiyne (DiPhDY) for use as the active cathode material in lithium-sulfur batteries. These sulfur-rich polymers exhibited excellent capacity retention (800 mA h g-1 at 300 cycles) and extended battery lifetimes of over 850 cycles at C/5 rate.

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Inverse vulcanization of elemental sulfur with 1,4-diphenylbutadiyne for cathode materials in Li-S batteries

Abstract

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