TY - JOUR
T1 - Iodosylperfluoroalkanes as reagents for the preparation of perfluoroalkyliodonium salts under aprotic conditions
AU - Zhdankin, Viktor
AU - Kuehl, Chris J.
AU - Simonsen, Angela J.
PY - 1996/1/1
Y1 - 1996/1/1
N2 - Iodosylperfluoroalkanes (CnF2n+1IO, n = 2,3,4,6) were prepared in high yield by mild hydrolysis of [bis(trifluoroacetoxy)iodo]perfluoroalkanes with sodium bicarbonate and ice. Reaction of iodosylperfluoroalkanes with 1,4-bis (trimethylsilyl) benzene in the presence of trimethylsilyltriflate gave the corresponding perfluoroalkyl(ary1) iodonium triflates in 70-83% yield.
AB - Iodosylperfluoroalkanes (CnF2n+1IO, n = 2,3,4,6) were prepared in high yield by mild hydrolysis of [bis(trifluoroacetoxy)iodo]perfluoroalkanes with sodium bicarbonate and ice. Reaction of iodosylperfluoroalkanes with 1,4-bis (trimethylsilyl) benzene in the presence of trimethylsilyltriflate gave the corresponding perfluoroalkyl(ary1) iodonium triflates in 70-83% yield.
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U2 - 10.1080/13583149612331338657
DO - 10.1080/13583149612331338657
M3 - Article
AN - SCOPUS:85013616298
SN - 1024-1221
VL - 1
SP - 349
EP - 352
JO - Main Group Chemistry
JF - Main Group Chemistry
IS - 3
ER -