Isolation of [Cp(CO)(Ph3P)FeNCCH3]+BF-4 from a vinylidene precursor; an organometallic Beckmann rearrangement

Anthony G.M. Barrett; Nancy E. Carpenter; Michal Sabat

doi:10.1016/0022-328X(88)83043-2

Isolation of [Cp(CO)(Ph₃P)FeNCCH₃]⁺BF^-₄ from a vinylidene precursor; an organometallic Beckmann rearrangement

Anthony G.M. Barrett, Nancy E. Carpenter, Michal Sabat

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Abstract

The reaction of [Cp(CO)(Ph₃P)FeCCH₂]⁺ BF^-₄ with several hydrazine derivatives yielded the acetonitrile complex [Cp(CO)(Ph₃P)Fe-NCCH₃]⁺ BF^-4 (4) (62-71%). The formation of this product is apparently the result of a facile Beckmann-type rearrangement.

Original language	English (US)
Pages (from-to)	C8-C12
Journal	Journal of Organometallic Chemistry
Volume	352
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(88)83043-2
State	Published - Sep 6 1988
Externally published	Yes

Bibliographical note

Funding Information:
Acknowtedgements. We thank the National Science Foundation (CHE-8500890) for the generous support of this program, the Midwest Center for Mass Spectrometry, an NSF Regional Instrument Facility (CHE-8211164) for obtaining mass spectral data and the National Institutes of Health (RR-02314) for the purchase of a 400 MHz NMR Spectrometer used in these studies.

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title = "Isolation of [Cp(CO)(Ph3P)FeNCCH3]+BF-4 from a vinylidene precursor; an organometallic Beckmann rearrangement",

abstract = "The reaction of [Cp(CO)(Ph3P)FeCCH2]+ BF-4 with several hydrazine derivatives yielded the acetonitrile complex [Cp(CO)(Ph3P)Fe-NCCH3]+ BF-4 (4) (62-71%). The formation of this product is apparently the result of a facile Beckmann-type rearrangement.",

author = "Barrett, {Anthony G.M.} and Carpenter, {Nancy E.} and Michal Sabat",

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T1 - Isolation of [Cp(CO)(Ph3P)FeNCCH3]+BF-4 from a vinylidene precursor; an organometallic Beckmann rearrangement

AU - Barrett, Anthony G.M.

AU - Carpenter, Nancy E.

AU - Sabat, Michal

N1 - Funding Information: Acknowtedgements. We thank the National Science Foundation (CHE-8500890) for the generous support of this program, the Midwest Center for Mass Spectrometry, an NSF Regional Instrument Facility (CHE-8211164) for obtaining mass spectral data and the National Institutes of Health (RR-02314) for the purchase of a 400 MHz NMR Spectrometer used in these studies.

PY - 1988/9/6

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N2 - The reaction of [Cp(CO)(Ph3P)FeCCH2]+ BF-4 with several hydrazine derivatives yielded the acetonitrile complex [Cp(CO)(Ph3P)Fe-NCCH3]+ BF-4 (4) (62-71%). The formation of this product is apparently the result of a facile Beckmann-type rearrangement.

AB - The reaction of [Cp(CO)(Ph3P)FeCCH2]+ BF-4 with several hydrazine derivatives yielded the acetonitrile complex [Cp(CO)(Ph3P)Fe-NCCH3]+ BF-4 (4) (62-71%). The formation of this product is apparently the result of a facile Beckmann-type rearrangement.

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